Quarterly Journal of the Chemical Society of London, Volume 7 |
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Page 1037
... mole - 1 and AS = ca. -29 e.u. At 25 ° a value K1 = 1.4 × 10-3 mole 1. - 1 gives k 3.7 × 104 1. mole - 1 sec . - 1 and since this is in excess of the rate constants for the inner - sphere complex- ing of thiocyanate with vanadium ( 1 ) ...
... mole - 1 and AS = ca. -29 e.u. At 25 ° a value K1 = 1.4 × 10-3 mole 1. - 1 gives k 3.7 × 104 1. mole - 1 sec . - 1 and since this is in excess of the rate constants for the inner - sphere complex- ing of thiocyanate with vanadium ( 1 ) ...
Page 1375
... mole - 2 sec . - 1 at 25 ° and μ = 5 · 00 . Equation ( 18 ) can also be deduced for the pseudo - first- order rate constant from equation ( 15 ) , and a plot of the left - hand side against [ QH2 ] should be linear at constant 2 ( kß1 + ...
... mole - 2 sec . - 1 at 25 ° and μ = 5 · 00 . Equation ( 18 ) can also be deduced for the pseudo - first- order rate constant from equation ( 15 ) , and a plot of the left - hand side against [ QH2 ] should be linear at constant 2 ( kß1 + ...
Page 1584
... mole ̄1 ) . 12.11.8 Copper 300 6.9 ± 0.4 TABLE 5 PK acid values for protonated forms of metal chelate complexes * At ... ( mole 1. - 1 ) Whence K , 100 2.360.18 400 1.55 0.09 500 1.41 0.08 = 3.23 ± 0.74 1. mole - 1 ( K2 = 0.38 510 nm .; pH ...
... mole ̄1 ) . 12.11.8 Copper 300 6.9 ± 0.4 TABLE 5 PK acid values for protonated forms of metal chelate complexes * At ... ( mole 1. - 1 ) Whence K , 100 2.360.18 400 1.55 0.09 500 1.41 0.08 = 3.23 ± 0.74 1. mole - 1 ( K2 = 0.38 510 nm .; pH ...
Contents
Inorganic physical and theoretical chemistry | 1001 |
J ROBINSON and C H L KENNARD | 1008 |
Nearestneighbour model for transfer of electronic excitation energy | 1016 |
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absorption acid Acta adducts Amer anion aqueous assigned atoms band benzene bond calculated cancrinite carbon cation Chem chemical chemical shifts Chemistry chloride cm.¹ co-ordination cobalt(II complex compounds concentration configuration crystals density effect electron energy enthalpy equation equilibrium ethanol experimental Figure fluorine formation frequency H₂O hydrogen i.r. spectrum increase Inorg intensity interaction iron(II k₁ ligand linear magnetic measured metal methaemoglobins method methyl mixture modes mole mole-¹ molecular molecule n.m.r. spectra niobium nitrogen Nujol observed obtained orbitals oxidation oxygen parameters peak perchlorate perchloric acid phenyl phosphine phosphorus Phys potassium prepared present proton pyridine radical Raman rate constant reaction resonance ring room temperature salt sample shift shown sodalite sodium solid solution solvent species spectra structure studied sulphur symmetry Table thiocyanate tion trans tributyl phosphate triphenylphosphine values vanadium(IV vibrations X-ray zeolite