Journal of the Chemical SocietyThe Society., 1948 |
From inside the book
Results 1-3 of 63
Page 304
... cyanide , base , and amidine ( 1 ) . When dissociation of the amidinium salt takes place , the relative volatility of the base and of the amidine will have an influence on the reaction . Ammonium and substituted - ammonium sulphonates ...
... cyanide , base , and amidine ( 1 ) . When dissociation of the amidinium salt takes place , the relative volatility of the base and of the amidine will have an influence on the reaction . Ammonium and substituted - ammonium sulphonates ...
Page 306
... Cyanide and 2 - Aminopyridine . - A mixture of the cyanide ( 9.05 g . ) and 2 - aminopyridine ( 4.7 g .; 1 mol . ) was kept at 180 ° for an hour and afforded unchanged cyanide ( 7 · 5 g .; 83 % ) and N - 2 - pyridyl - p ...
... Cyanide and 2 - Aminopyridine . - A mixture of the cyanide ( 9.05 g . ) and 2 - aminopyridine ( 4.7 g .; 1 mol . ) was kept at 180 ° for an hour and afforded unchanged cyanide ( 7 · 5 g .; 83 % ) and N - 2 - pyridyl - p ...
Page 680
... cyanide . A solution of 30 g . of sodium cyanide in 40 ml . of water was mixed with a solution of 100 g . of n - amyl iodide in 125 ml . of methyl alcohol , and the whole refluxed for 30 hours : no solid separated . The crude cyanide ...
... cyanide . A solution of 30 g . of sodium cyanide in 40 ml . of water was mixed with a solution of 100 g . of n - amyl iodide in 125 ml . of methyl alcohol , and the whole refluxed for 30 hours : no solid separated . The crude cyanide ...
Contents
kilocals as the free energy difference contributed by the hyperconjugated methyl group | 373 |
SIR WILLIAM RAMSAY AND Ralph Forster LABORATORIES | 417 |
control of anionotropic rearrangement and of the significance of conjugation and hypercon | 440 |
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Common terms and phrases
4-dideuterobenzene absorption spectrum acetic acid acetic anhydride acetone added alkaline Amer ammonia analcite aqueous sodium atoms bands benzene boiling bond bromine Calc carbon catalyst CH₂ chabazite Chem chloride chloroform colourless needles compound concentrated cooled corresponding crystallised from alcohol crystals cyanide D.Sc decomp derivative dilute dissolved distilled dried electronic origin energy ester ethanol ether evaporated excited extracted filtered filtrate fluorescence formed Found fraction fundamental frequencies gave give H₂O heated hexadeuterobenzene hydrochloric acid hydrogen hydrogen chloride hydrolysis Ingold isolated kcals ketone light petroleum method methyl alcohol mixed m. p. mixture molecule obtained oxidation peroxide phenol potassium potassium hydroxide precipitated prepared prisms pyridine reaction reduced pressure refluxed requires residue room temperature salt separated sodium hydroxide solid soluble solution solvent spectra structure sulphide sulphuric acid symmetry transitions unsaturated upper electronic upper-state vibration washed yellow needles yield