Journal of the Chemical SocietyThe Society., 1948 |
From inside the book
Results 1-3 of 70
Page 269
... ethanol to ether and ethylene , and under the conditions used , ethylene was the principal product . The reactant mixture was a solution of ethanol in water , containing 93 % of ethanol by weight . This was stored in a reservoir under ...
... ethanol to ether and ethylene , and under the conditions used , ethylene was the principal product . The reactant mixture was a solution of ethanol in water , containing 93 % of ethanol by weight . This was stored in a reservoir under ...
Page 522
... ethanol ( from 1.1 g . of sodium and 35 c.c. of ethanol ) . The mixture was refluxed for 1 hour , filtered , and the filtrate evaporated . The residue was treated with water and the product isolated by means of ether ...
... ethanol ( from 1.1 g . of sodium and 35 c.c. of ethanol ) . The mixture was refluxed for 1 hour , filtered , and the filtrate evaporated . The residue was treated with water and the product isolated by means of ether ...
Page 797
... ethanol have also been studied ( Table IV ) . With regard to the rearrangement , the results are exactly parallel with those obtained for aqueous dioxan . Just as with the carbinol , the rate constants are only slightly higher in the ...
... ethanol have also been studied ( Table IV ) . With regard to the rearrangement , the results are exactly parallel with those obtained for aqueous dioxan . Just as with the carbinol , the rate constants are only slightly higher in the ...
Contents
kilocals as the free energy difference contributed by the hyperconjugated methyl group | 373 |
SIR WILLIAM RAMSAY AND Ralph Forster LABORATORIES | 417 |
control of anionotropic rearrangement and of the significance of conjugation and hypercon | 440 |
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4-dideuterobenzene absorption spectrum acetic acid acetic anhydride acetone added alkaline Amer ammonia analcite aqueous sodium atoms bands benzene boiling bond bromine Calc carbon catalyst CH₂ chabazite Chem chloride chloroform colourless needles compound concentrated cooled corresponding crystallised from alcohol crystals cyanide D.Sc decomp derivative dilute dissolved distilled dried electronic origin energy ester ethanol ether evaporated excited extracted filtered filtrate fluorescence formed Found fraction fundamental frequencies gave give H₂O heated hexadeuterobenzene hydrochloric acid hydrogen hydrogen chloride hydrolysis Ingold isolated kcals ketone light petroleum method methyl alcohol mixed m. p. mixture molecule obtained oxidation peroxide phenol potassium potassium hydroxide precipitated prepared prisms pyridine reaction reduced pressure refluxed requires residue room temperature salt separated sodium hydroxide solid soluble solution solvent spectra structure sulphide sulphuric acid symmetry transitions unsaturated upper electronic upper-state vibration washed yellow needles yield