Journal of the Chemical SocietyThe Society., 1964 "Titles of chemical papers in British and foreign journals" included in Quarterly journal, v. 1-12. |
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Page 353
... Diazomethane and Acetone in the Presence of Hydroxylic Compounds . By J. N. BRADLEY , G. W. COWELL , and A. LEDWITH . Photolysis of diazomethane in acetone containing hydroxylic compounds produces mainly ethyl methyl ketone and 2,2 ...
... Diazomethane and Acetone in the Presence of Hydroxylic Compounds . By J. N. BRADLEY , G. W. COWELL , and A. LEDWITH . Photolysis of diazomethane in acetone containing hydroxylic compounds produces mainly ethyl methyl ketone and 2,2 ...
Page 356
... diazomethane or acetone , since the sequence parallels the probable hydrogen bonding efficiency . Additives such as butan - 1 - ol do not affect the reaction of diazomethane with cyclo- hexene to give products characteristic of C = C ...
... diazomethane or acetone , since the sequence parallels the probable hydrogen bonding efficiency . Additives such as butan - 1 - ol do not affect the reaction of diazomethane with cyclo- hexene to give products characteristic of C = C ...
Page 357
... diazomethane in solution cannot be assumed to involve carbene without further justification . Diazomethane is isoelectronic with nitrous oxide and hydrazoic acid , and the electronic structures of these two molecules have been discussed ...
... diazomethane in solution cannot be assumed to involve carbene without further justification . Diazomethane is isoelectronic with nitrous oxide and hydrazoic acid , and the electronic structures of these two molecules have been discussed ...
Contents
NO PAGE | 1 |
Nucleophilic reactivity Part IV Competing bimolecular substitution | 5 |
The biosynthesis of fungal metabolites Part I Two different pathways | 16 |
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absorption acetic acid acetic anhydride alkaline aluminium chloride Amer amine ammonia anhydride aqueous aromatic atoms band benzene bond bromide Calc carbon Chem chloride chloroform chromatography complex compound concentration coupling constants crystallised crystals decomp decomposition derivative dilute dimethyl dimethyl ether dioxan distilled dried Elution equation erythroaphin-fb erythroaphins ester ethanol ether ethyl ethyl acetate evaporated EXPERIMENTAL extracted formation Found fraction gave halides hydrochloric acid hydrogen hydrolysis infrared infrared spectra iodide irradiated isomer k₂ ligand light petroleum m. p. and mixed maltose manganese(III method mixed m. p. mixture mole molecule mµ log nitrogen obtained oxidation oxygen phenyl piperidine potassium precipitate prepared protoaphin proton pyridine quinone reaction recrystallised reflux requires residue room temperature salt sample sodium hydroxide solution solvent spectrum structure substitution Table ultraviolet values Vmax washed yellow yield