Journal of the Chemical Society, Part 4, Pages 3513-4668The Society., 1964 "Titles of chemical papers in British and foreign journals" included in Quarterly journal, v. 1-12. |
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Page 3912
... salt effects on this reaction in dimethyl sulphoxide . The observed effects appear to be dominantly specific , and , in some cases to depend on both ions of the salt . The effects may be either retarding or accelerating , as exemplified ...
... salt effects on this reaction in dimethyl sulphoxide . The observed effects appear to be dominantly specific , and , in some cases to depend on both ions of the salt . The effects may be either retarding or accelerating , as exemplified ...
Page 4347
... salt 12 is reasonable . Hutchison and Pastor 12 found minimum widths for potassium solutions at -25 , 0 , and 33 ... salt concentrations . a , Rb + RbI , molality of salt , RbBr , molality of salt , 7 , molality of salt , 12 , 0-2 ; 1 ...
... salt 12 is reasonable . Hutchison and Pastor 12 found minimum widths for potassium solutions at -25 , 0 , and 33 ... salt concentrations . a , Rb + RbI , molality of salt , RbBr , molality of salt , 7 , molality of salt , 12 , 0-2 ; 1 ...
Page 4385
... salts and dialkyl- thallic salts . It would seem that such a dealkylation could hardly fail to go when the electrophile was a thallic salt . We would then obtain an alkylthallic salt , if it is stable : RHgR + TIX3 RHgX + RTIX2 We tried ...
... salts and dialkyl- thallic salts . It would seem that such a dealkylation could hardly fail to go when the electrophile was a thallic salt . We would then obtain an alkylthallic salt , if it is stable : RHgR + TIX3 RHgX + RTIX2 We tried ...
Contents
4028 | 3507 |
Nucleophilic reactivity | 3513 |
Molecular polarisability Dipole moments molar Kerr constants and apparent | 3523 |
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absorption acetic acid acetic anhydride acetone acetoxylation acetyl added alcohol alkaline alumina aluminium Amer amine atoms band benzene benzyl bond bromide Calc carbon carbonyl chabazite Chem chloride chloroform chromatography cm.¹ compounds concentration crystals decomp diethyl diluted dimethylformamide diol dissolved distilled dried ester ethanol ethyl acetate evaporated EXPERIMENTAL extracted with ether filtrate formation Found fraction gave give heated hydrochloric acid hydrochloride hydrogen hydrolysis hydroxyl infrared iodide isomers K₁ ketone light petroleum lithium lithium aluminium hydride log ɛ m. p. and mixed mixed m. p. mixture mole molecules needles nitrate nitric acid nitrogen o-xylene obtained optical oxide oxygen petroleum b. p. phenol picrate potassium precipitated prepared proton pyridine rate constants reaction recrystallised refluxed requires residue room temperature salt sodium hydroxide solvent spectra spectrum stirred structure substitution sulphuric acid Table values washed yield