Journal of the Chemical Society, Part 4, Pages 3513-4668The Society., 1964 "Titles of chemical papers in British and foreign journals" included in Quarterly journal, v. 1-12. |
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Page 3695
... acid concentration is depicted in Fig . 1 ( C ) . The slope of the log - log plot is 2.31 . Another set of runs was ... sulphuric acid was added . Runs 36 and 41 are typical and illustrate the marked catalytic effect of very small ...
... acid concentration is depicted in Fig . 1 ( C ) . The slope of the log - log plot is 2.31 . Another set of runs was ... sulphuric acid was added . Runs 36 and 41 are typical and illustrate the marked catalytic effect of very small ...
Page 3700
... sulphuric acid ; hence [ AcOH ] = [ AcO • NO2 ] . The increased rate on addition of sulphuric acid is thus predicted to be of first order in sulphuric acid , and of between zeroth and second order in nitric acid ( in the absence of added ...
... sulphuric acid ; hence [ AcOH ] = [ AcO • NO2 ] . The increased rate on addition of sulphuric acid is thus predicted to be of first order in sulphuric acid , and of between zeroth and second order in nitric acid ( in the absence of added ...
Page 4023
... acid . Chromium trioxide ( 0 · 25 g . ) dissolved in glacial acetic acid ( 2 · 5 ml . ) and water ( 3 drops ) , and ... sulphuric acid ( 2 drops ) was added and the brown solution left at room temperature for 1 week . Dilution with ...
... acid . Chromium trioxide ( 0 · 25 g . ) dissolved in glacial acetic acid ( 2 · 5 ml . ) and water ( 3 drops ) , and ... sulphuric acid ( 2 drops ) was added and the brown solution left at room temperature for 1 week . Dilution with ...
Contents
4028 | 3507 |
Nucleophilic reactivity | 3513 |
Molecular polarisability Dipole moments molar Kerr constants and apparent | 3523 |
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absorption acetic acid acetic anhydride acetone acetoxylation acetyl added alcohol alkaline alumina aluminium Amer amine atoms band benzene benzyl bond bromide Calc carbon carbonyl chabazite Chem chloride chloroform chromatography cm.¹ compounds concentration crystals decomp diethyl diluted dimethylformamide diol dissolved distilled dried ester ethanol ethyl acetate evaporated EXPERIMENTAL extracted with ether filtrate formation Found fraction gave give heated hydrochloric acid hydrochloride hydrogen hydrolysis hydroxyl infrared iodide isomers K₁ ketone light petroleum lithium lithium aluminium hydride log ɛ m. p. and mixed mixed m. p. mixture mole molecules needles nitrate nitric acid nitrogen o-xylene obtained optical oxide oxygen petroleum b. p. phenol picrate potassium precipitated prepared proton pyridine rate constants reaction recrystallised refluxed requires residue room temperature salt sodium hydroxide solvent spectra spectrum stirred structure substitution sulphuric acid Table values washed yield