Quarterly Journal of the Chemical Society of London, Part 1, Pages 809-1856 |
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Page 1092
... decaborane , first because the preparative reaction conditions are very mild and secondly because decaborane can be re - formed from the product by destructive sublimation under high vacuum at room temperature . Moreover , the species ...
... decaborane , first because the preparative reaction conditions are very mild and secondly because decaborane can be re - formed from the product by destructive sublimation under high vacuum at room temperature . Moreover , the species ...
Page 1093
... decaborane with trimethylamine - mono- chloroalane and with trimethylamine - diethylalane do not proceed in benzene , but only in the presence of ether ; this was found to be typical of the reaction of deca- borane and trimethylamine ...
... decaborane with trimethylamine - mono- chloroalane and with trimethylamine - diethylalane do not proceed in benzene , but only in the presence of ether ; this was found to be typical of the reaction of deca- borane and trimethylamine ...
Page 1094
... Decaborane and Trimethylamine - Trideutero- alane . - Trimethylamine - trideuteroalane ( 0-274 g . , 2.98 mmoles ) in ether was added to decaborane ( 0.365 g . , 3.00 mmoles ) in ether at -40 ° . A white solid was precipitated . As the ...
... Decaborane and Trimethylamine - Trideutero- alane . - Trimethylamine - trideuteroalane ( 0-274 g . , 2.98 mmoles ) in ether was added to decaborane ( 0.365 g . , 3.00 mmoles ) in ether at -40 ° . A white solid was precipitated . As the ...
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absorption acetone acid adducts Amer amine anion aqueous assigned bands benzene bond bromide Calc calculated carbon carbonyl cation Chem CHEMISTRY chloride cm.¹ co-ordination cobalt cobalt(II coefficients complexes compounds concentration copper(II crystallised crystals decaborane decomposition derivatives diethyl ether dimer effect electron energy equation ethanol ether EXPERIMENTAL Figure Found frequency function germania groups H₂O halide heated hydration hydrazine hydride hydrogen hydrolysis hydroxide indium indium(III infrared infrared spectra Inorg intensity interactions iodide ionic isomer kcal ligand liquid measured methyl mixture mmole molar mole mole¹ molecular molecules nitrate nitrogen observed obtained octahedral orbital oxide oxygen peaks pentachloride perchlorate phosphorus Phys prepared protactinium proton pyridine rate constants reaction resin room temperature salts similar sodium solid soluble solution solvent solvolysis species spectrum steric structure sulphate symmetry Table tetrahedral tetrahydrofuran thermal trans vacuo values vanadyl ion vibrations X-ray