Quarterly Journal of the Chemical Society of London, Part 1, Pages 809-1856 |
From inside the book
Results 1-3 of 43
Page 1069
... diethyl ether complexes , from R , Be , BeBr2 , and LiH . The liquid diethyl ether complex of methylberyllium hydride is a dimer , ( MeBeH , Et2O ) , in benzene like the pyridine complex ( MeBeH , py ) 2 . About five - sixths of the ether ...
... diethyl ether complexes , from R , Be , BeBr2 , and LiH . The liquid diethyl ether complex of methylberyllium hydride is a dimer , ( MeBeH , Et2O ) , in benzene like the pyridine complex ( MeBeH , py ) 2 . About five - sixths of the ether ...
Page 1071
... ether and benzene . d then gave 95 % of 1 - bromo- and 5 % of 2 - bromo - pentane . 95 % of cis - isomer . d After ... diethyl ether ( 200 c.c. ) , to which beryllium bromide ( 4.43 g . ) and di- methylberyllium ( 18.3 c.c. of 1.43M ...
... ether and benzene . d then gave 95 % of 1 - bromo- and 5 % of 2 - bromo - pentane . 95 % of cis - isomer . d After ... diethyl ether ( 200 c.c. ) , to which beryllium bromide ( 4.43 g . ) and di- methylberyllium ( 18.3 c.c. of 1.43M ...
Page 1072
... diethyl ether showed no sign of decomposition during 3 hr . at room temperature but immediately turned orange ( formation of bispyridine aminomethylberyllium complex , see below ) when pyridine was added . Reaction between ...
... diethyl ether showed no sign of decomposition during 3 hr . at room temperature but immediately turned orange ( formation of bispyridine aminomethylberyllium complex , see below ) when pyridine was added . Reaction between ...
Other editions - View all
Common terms and phrases
absorption acetone acid adducts Amer amine anion aqueous assigned bands benzene bond bromide Calc calculated carbon carbonyl cation Chem CHEMISTRY chloride cm.¹ co-ordination cobalt cobalt(II coefficients complexes compounds concentration copper(II crystallised crystals decaborane decomposition derivatives diethyl ether dimer effect electron energy equation ethanol ether EXPERIMENTAL Figure Found frequency function germania groups H₂O halide heated hydration hydrazine hydride hydrogen hydrolysis hydroxide indium indium(III infrared infrared spectra Inorg intensity interactions iodide ionic isomer kcal ligand liquid measured methyl mixture mmole molar mole mole¹ molecular molecules nitrate nitrogen observed obtained octahedral orbital oxide oxygen peaks pentachloride perchlorate phosphorus Phys prepared protactinium proton pyridine rate constants reaction resin room temperature salts similar sodium solid soluble solution solvent solvolysis species spectrum steric structure sulphate symmetry Table tetrahedral tetrahydrofuran thermal trans vacuo values vanadyl ion vibrations X-ray