Quarterly Journal of the Chemical Society of London, Part 1, Pages 809-1856 |
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Page 1082
... ligand to 1570 in the complexes , so both adducts involve oxygen - bonded urea . 18 Dimethyl sulphoxide ( dmso ) reacts readily with all three indium ( III ) halides , yielding InX ( dmso ) , with chloride and bromide , and InI , ( dmso ) ...
... ligand to 1570 in the complexes , so both adducts involve oxygen - bonded urea . 18 Dimethyl sulphoxide ( dmso ) reacts readily with all three indium ( III ) halides , yielding InX ( dmso ) , with chloride and bromide , and InI , ( dmso ) ...
Page 1541
... ligand more closely akin to those present in enzymic systems . For such ligands , the individual chelate rings are more nearly planar than those in diamine rings , and stereoselectivity probably arises from the interactions between ...
... ligand more closely akin to those present in enzymic systems . For such ligands , the individual chelate rings are more nearly planar than those in diamine rings , and stereoselectivity probably arises from the interactions between ...
Page 1771
... ligand distances . Either of these would be consistent with some covalency in the metal- ligand bond . It therefore seemed worthwhile also to attempt to correlate our results using McClure's empirical mole- cular orbital approach . In ...
... ligand distances . Either of these would be consistent with some covalency in the metal- ligand bond . It therefore seemed worthwhile also to attempt to correlate our results using McClure's empirical mole- cular orbital approach . In ...
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absorption acetone acid adducts Amer amine anion aqueous assigned bands benzene bond bromide Calc calculated carbon carbonyl cation Chem CHEMISTRY chloride cm.¹ co-ordination cobalt cobalt(II coefficients complexes compounds concentration copper(II crystallised crystals decaborane decomposition derivatives diethyl ether dimer effect electron energy equation ethanol ether EXPERIMENTAL Figure Found frequency function germania groups H₂O halide heated hydration hydrazine hydride hydrogen hydrolysis hydroxide indium indium(III infrared infrared spectra Inorg intensity interactions iodide ionic isomer kcal ligand liquid measured methyl mixture mmole molar mole mole¹ molecular molecules nitrate nitrogen observed obtained octahedral orbital oxide oxygen peaks pentachloride perchlorate phosphorus Phys prepared protactinium proton pyridine rate constants reaction resin room temperature salts similar sodium solid soluble solution solvent solvolysis species spectrum steric structure sulphate symmetry Table tetrahedral tetrahydrofuran thermal trans vacuo values vanadyl ion vibrations X-ray