Quarterly Journal of the Chemical Society of London, Part 1, Pages 809-1856 |
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Page 1166
... perchlorate in 1,2 - dichloroethane Λ 104 [ Ph2CCIO ] ( ohm - 1 Temp . ( M ) cm.2 ) Temp . A 104 [ Ph2CCIO1 ] ( ohm - 1 ( M ) cm.2 ) 21.5 ° 0.167 58.7 10 ° 1.67 49.7 0.353 64.0 1.96 47.7 1.25 58.1 7.87 39.5 1.66 57.7 8.94 38.3 1.93 55.3 ...
... perchlorate in 1,2 - dichloroethane Λ 104 [ Ph2CCIO ] ( ohm - 1 Temp . ( M ) cm.2 ) Temp . A 104 [ Ph2CCIO1 ] ( ohm - 1 ( M ) cm.2 ) 21.5 ° 0.167 58.7 10 ° 1.67 49.7 0.353 64.0 1.96 47.7 1.25 58.1 7.87 39.5 1.66 57.7 8.94 38.3 1.93 55.3 ...
Page 1201
... perchlorate ( Figure 3 ) . The formulation of the blue isomer as bistri- ( 2 - pyridyl ) - aminecopper ( II ) perchlorate ( terdentate ligands ) is Preparations . - Tri- ( 2 - pyridyl ) amine. Optical density ( orbitrary units ) 20,000 ...
... perchlorate ( Figure 3 ) . The formulation of the blue isomer as bistri- ( 2 - pyridyl ) - aminecopper ( II ) perchlorate ( terdentate ligands ) is Preparations . - Tri- ( 2 - pyridyl ) amine. Optical density ( orbitrary units ) 20,000 ...
Page 1601
... perchlorate was prepared by repeated evaporation of a known weight of ignited oxide with perchloric acid . total perchlorate concentration was determined by passing an aliquot portion of the stock solution through a cation- exchange ...
... perchlorate was prepared by repeated evaporation of a known weight of ignited oxide with perchloric acid . total perchlorate concentration was determined by passing an aliquot portion of the stock solution through a cation- exchange ...
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absorption acetone acid adducts Amer amine anion aqueous assigned bands benzene bond bromide Calc calculated carbon carbonyl cation Chem CHEMISTRY chloride cm.¹ co-ordination cobalt cobalt(II coefficients complexes compounds concentration copper(II crystallised crystals decaborane decomposition derivatives diethyl ether dimer effect electron energy equation ethanol ether EXPERIMENTAL Figure Found frequency function germania groups H₂O halide heated hydration hydrazine hydride hydrogen hydrolysis hydroxide indium indium(III infrared infrared spectra Inorg intensity interactions iodide ionic isomer kcal ligand liquid measured methyl mixture mmole molar mole mole¹ molecular molecules nitrate nitrogen observed obtained octahedral orbital oxide oxygen peaks pentachloride perchlorate phosphorus Phys prepared protactinium proton pyridine rate constants reaction resin room temperature salts similar sodium solid soluble solution solvent solvolysis species spectrum steric structure sulphate symmetry Table tetrahedral tetrahydrofuran thermal trans vacuo values vanadyl ion vibrations X-ray