Journal of the Chemical Society, Part 1Chemical Society., 1946 |
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Page 24
... addition of a further 2 c.c. of acetic acid and 3 c.c. of water , including any water or acetic acid added with the poison or with the detoxicant . This amount of carbon disulphide was sufficient , while in its normal toxic state , to ...
... addition of a further 2 c.c. of acetic acid and 3 c.c. of water , including any water or acetic acid added with the poison or with the detoxicant . This amount of carbon disulphide was sufficient , while in its normal toxic state , to ...
Page 25
... addition ( as reagent ) being made at room temperature and the remaining additions ( hydrogen peroxide alone ) at 80-85 ° without intermediate cooling . Complete detoxication was reached at a somewhat higher hydrogen peroxide content ...
... addition ( as reagent ) being made at room temperature and the remaining additions ( hydrogen peroxide alone ) at 80-85 ° without intermediate cooling . Complete detoxication was reached at a somewhat higher hydrogen peroxide content ...
Page 47
... addition could conceivably occur at either the ethylenic or acetylenic linkages ; the light absorption of the adducts shows , however , addition at the triple bond as indicated below . This point has been NHRR . Me.CH.CH.CO • C ; CH ...
... addition could conceivably occur at either the ethylenic or acetylenic linkages ; the light absorption of the adducts shows , however , addition at the triple bond as indicated below . This point has been NHRR . Me.CH.CH.CO • C ; CH ...
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Common terms and phrases
4-dideuterobenzene absorption acetic acid acetic anhydride acetone activity added alkaline alkyl Amer ammonia antimalarial atoms band benzene bimolecular boiling bromide Calc carbinol CH₂ Chem chloride chloroform colourless needles combination tones compound condensation cooled corresponding crude crystallised from alcohol decomp derivatives deuterated benzenes deuterium dilute dissolved distilled dried effect ester ether ethyl alcohol evaporated extracted filtered formed Found fraction fundamental frequencies gave give b. p. halides heated hexadeuterobenzene hydrochloric acid hydrogen hydrolysis infra-red spectrum iodide isolated ketone ligroin mannitol methanol method mixture molecule monodeuterobenzene neopentyl normal co-ordinates obtained oxide phosphoryl chloride potassium praseodymium precipitate prepared prisms pyridine Raman spectrum reaction reagent rearrangement reduced pressure refluxed requires residue salt semicarbazone separated sodium carbonate sodium hydroxide solid soluble solution solvent sorbitol spectra steric stirred structure substitution sulphuric acid symmetry class Table temperature washed yellow needles yield