Journal of the Chemical Society, Part 1Chemical Society., 1946 |
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Page 166
... solvent - these being diagnostic features shown by the solvolytic reactions of certain other halides ( e.g. , tert ... solvent , ( b ) the effect on reaction rate of increasing the ionising capacity of the solvent , ( c ) the nature of ...
... solvent - these being diagnostic features shown by the solvolytic reactions of certain other halides ( e.g. , tert ... solvent , ( b ) the effect on reaction rate of increasing the ionising capacity of the solvent , ( c ) the nature of ...
Page 167
... solvent variation is , in some respects , not so critical and conclusive as the effect described above , but it provides useful auxiliary evidence of mechanism . Both mechanisms should be facilitated by passing to a more aqueous solvent ...
... solvent variation is , in some respects , not so critical and conclusive as the effect described above , but it provides useful auxiliary evidence of mechanism . Both mechanisms should be facilitated by passing to a more aqueous solvent ...
Page 168
... solvent ( Part XXXI ) it is of the order of magnitude of the measured rates for other primary bromides , which , in that solvent , we believe to be undergoing unimolecular solvolysis . EXPERIMENTAL . " Materials . neoPentyl bromide was ...
... solvent ( Part XXXI ) it is of the order of magnitude of the measured rates for other primary bromides , which , in that solvent , we believe to be undergoing unimolecular solvolysis . EXPERIMENTAL . " Materials . neoPentyl bromide was ...
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Common terms and phrases
4-dideuterobenzene absorption acetic acid acetic anhydride acetone activity added alkaline alkyl Amer ammonia antimalarial atoms band benzene bimolecular boiling bromide Calc carbinol CHâ‚‚ Chem chloride chloroform colourless needles combination tones compound condensation cooled corresponding crude crystallised from alcohol decomp derivatives deuterated benzenes deuterium dilute dissolved distilled dried effect ester ether ethyl alcohol evaporated extracted filtered formed Found fraction fundamental frequencies gave give b. p. halides heated hexadeuterobenzene hydrochloric acid hydrogen hydrolysis infra-red spectrum iodide isolated ketone ligroin mannitol methanol method mixture molecule monodeuterobenzene neopentyl normal co-ordinates obtained oxide phosphoryl chloride potassium praseodymium precipitate prepared prisms pyridine Raman spectrum reaction reagent rearrangement reduced pressure refluxed requires residue salt semicarbazone separated sodium carbonate sodium hydroxide solid soluble solution solvent sorbitol spectra steric stirred structure substitution sulphuric acid symmetry class Table temperature washed yellow needles yield