Quarterly Journal of the Chemical Society of London, Volume 7 |
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Page 1118
... acid determined by mixing sulphur trioxide with excess of hydrogen fluoride in fluorosulphuric acid was 189.4 ± 0.6 kcal./mole at 25 ° . The heat of formation of chlorosulphuric acid determined by hydrolysing the acid was 142.9 ± 0.4 ...
... acid determined by mixing sulphur trioxide with excess of hydrogen fluoride in fluorosulphuric acid was 189.4 ± 0.6 kcal./mole at 25 ° . The heat of formation of chlorosulphuric acid determined by hydrolysing the acid was 142.9 ± 0.4 ...
Page 1121
... acid being the more dissociated . Fluorosulphuric acid is less stable in the gas phase than at room temperature . At its b . p . 0-007 moles of sulphur trioxide and hydrogen fluoride would be in equilibrium with one mole of the acid ...
... acid being the more dissociated . Fluorosulphuric acid is less stable in the gas phase than at room temperature . At its b . p . 0-007 moles of sulphur trioxide and hydrogen fluoride would be in equilibrium with one mole of the acid ...
Page 1796
... acid - catalysed aquation of trans - dinitrobis- ( aa - bipyridyl ) cobalt ( III ) nitrate has been studied over the tempera- ture range 50-70 ° at an ionic strength of 2.5M . In the acid range [ H + ] = 0 · 1-2.5M the increase in rate ...
... acid - catalysed aquation of trans - dinitrobis- ( aa - bipyridyl ) cobalt ( III ) nitrate has been studied over the tempera- ture range 50-70 ° at an ionic strength of 2.5M . In the acid range [ H + ] = 0 · 1-2.5M the increase in rate ...
Contents
Inorganic physical and theoretical chemistry | 1001 |
The oxidation of some phosphinesubstituted chromium carbonyls | 1007 |
The preparation and magnetic properties of some oxybridged binuclear ironII Schiffbase complexes | 1014 |
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absorption acetone acid adduct alcohol Amer amine aqueous assigned ation atoms bands benzene bond bromide Calc calculated carbon carbonyl cell Chem Chemistry chloride chloroform cm.¹ co-ordinated cobalt cobalt(II complexes compounds concentration coupling constants crystals cyanide D.Sc decomposition derivatives dichloromethane dimeric electron electron spin resonance energy equation ethanol ether EXPERIMENTAL Figure formation formed Found groups H₂O halides heat hydrogen hydrogen chloride hydrolysis indium(III infrared infrared spectrum Inorg intensity iodide kcal kcal./mole kilchoanite ligand liquid magnetic measured metal methyl mixture mmoles modes mole molecular molecules n.m.r. spectra nickel nitrate nitrogen Nujol observed obtained orbital oxidation oxygen palladium parameters perchlorate phosphine Phys platinum(II potassium precipitate prepared proton pyridine Raman reaction recrystallised resonance room temperature salts sample selenophen shows similar sodium solid soluble solution solvent species spectra structure sulphur symmetry Table thermal trans values vibrations yellow yield