Quarterly Journal of the Chemical Society of London, Volume 7 |
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Page 1118
... heat of formation of fluorosulphuric acid determined by mixing sulphur trioxide with excess of hydrogen fluoride in fluorosulphuric acid was 189.4 ± 0.6 kcal./mole at 25 ° . The heat of formation of chlorosulphuric acid determined by ...
... heat of formation of fluorosulphuric acid determined by mixing sulphur trioxide with excess of hydrogen fluoride in fluorosulphuric acid was 189.4 ± 0.6 kcal./mole at 25 ° . The heat of formation of chlorosulphuric acid determined by ...
Page 1119
... heat of reaction given in Table 1 will swamp the heat of solution given in Table 2. Hydrogen fluoride ( mid- fraction from a cylinder of grade suitable for fluorine generators ) was condensed into a copper container and immersed in the ...
... heat of reaction given in Table 1 will swamp the heat of solution given in Table 2. Hydrogen fluoride ( mid- fraction from a cylinder of grade suitable for fluorine generators ) was condensed into a copper container and immersed in the ...
Page 1120
... heat measurements . overall error of 0.3 kcal./mole in the heat of formation of fluorosulphuric acid owing to errors in the heat of polymerisation of hydrogen fluoride seems a reasonable estimate . Thus the acids in the liquid or ...
... heat measurements . overall error of 0.3 kcal./mole in the heat of formation of fluorosulphuric acid owing to errors in the heat of polymerisation of hydrogen fluoride seems a reasonable estimate . Thus the acids in the liquid or ...
Contents
Inorganic physical and theoretical chemistry | 1001 |
The oxidation of some phosphinesubstituted chromium carbonyls | 1007 |
The preparation and magnetic properties of some oxybridged binuclear ironII Schiffbase complexes | 1014 |
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absorption acetone acid adduct alcohol Amer amine aqueous assigned ation atoms bands benzene bond bromide Calc calculated carbon carbonyl cell Chem Chemistry chloride chloroform cm.¹ co-ordinated cobalt cobalt(II complexes compounds concentration coupling constants crystals cyanide D.Sc decomposition derivatives dichloromethane dimeric electron electron spin resonance energy equation ethanol ether EXPERIMENTAL Figure formation formed Found groups H₂O halides heat hydrogen hydrogen chloride hydrolysis indium(III infrared infrared spectrum Inorg intensity iodide kcal kcal./mole kilchoanite ligand liquid magnetic measured metal methyl mixture mmoles modes mole molecular molecules n.m.r. spectra nickel nitrate nitrogen Nujol observed obtained orbital oxidation oxygen palladium parameters perchlorate phosphine Phys platinum(II potassium precipitate prepared proton pyridine Raman reaction recrystallised resonance room temperature salts sample selenophen shows similar sodium solid soluble solution solvent species spectra structure sulphur symmetry Table thermal trans values vibrations yellow yield