Quarterly Journal of the Chemical Society of London, Issue 1, Pages 1-844 |
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Page 276
... methanol , acetonylCo ( salen ) with methanol ] have been determined by X - ray structural analysis . As a part of a research programme on oxygen - carrying compounds we have resolved , by X - ray diffraction analysis , the crystal ...
... methanol , acetonylCo ( salen ) with methanol ] have been determined by X - ray structural analysis . As a part of a research programme on oxygen - carrying compounds we have resolved , by X - ray diffraction analysis , the crystal ...
Page 277
... methanol group ( Co - O 2.20 ± 0.02 Å ) and the carbonyl group of the acetonyl ligand is bonded to another molecule ( Co - C 2.02 ± 0 · 02 Å ) . In ( II ) the two trans - positions are occupied by a pyridine ( Co - N = 2.03 ± 0.01 Å ) ...
... methanol group ( Co - O 2.20 ± 0.02 Å ) and the carbonyl group of the acetonyl ligand is bonded to another molecule ( Co - C 2.02 ± 0 · 02 Å ) . In ( II ) the two trans - positions are occupied by a pyridine ( Co - N = 2.03 ± 0.01 Å ) ...
Page 711
... methanol matrix at -196 ° gave only the Wolff rearrange- ment product , methylketen , which was isolated as the methanol adduct ; traces of methoxyacetone were also experiment in the presence of methanol the precursor of acetone cannot ...
... methanol matrix at -196 ° gave only the Wolff rearrange- ment product , methylketen , which was isolated as the methanol adduct ; traces of methoxyacetone were also experiment in the presence of methanol the precursor of acetone cannot ...
Contents
The Wittig Rearrangement of Some Allyl Ethers by V RAUTENSTRAUCH | 4 |
The Mechanism of the Thermal Rearrangement of 1Substituted 1HAzepines to 6Aminofulvenes | 10 |
A Twoelectron Hydrogen Bridge Bond in Crystalline Trimethylaluminium Dimer by SUSAN K BYRAM | 16 |
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Common terms and phrases
absorption acetic acetonitrile acid Acta adduct alcohol alkaloids alkyl Amax Amer aqueous aromatic assigned atoms band benzene bond lengths bromide calculated carbanion carbon carbonyl chelate Chem Chemical Society Chim chloride cm-¹ co-ordinated Comm complex compounds configuration corresponding crystal structure cyclic Department of Chemistry derivatives dimer electron energy enol ester ether Figure formation formed gave hydrogen hydrolysis i.r. spectra ibid indicated Inorg intermediate irradiation isolated isomeric isomers ketone ligand mass spectrum metal methanol methylene mixture molecular molecule n.m.r. spectrum nitrogen observed obtained orbital oxidation oxygen peaks phenyl photolysis Phys planar presence protons pyridine radical ratio reaction reagent rearrangement Received reduction reported resonance ring room temperature salt shown singlet sodium solution solvent space group spectroscopic stereochemistry suggested sulphur Summary synthesis Tetrahedron Letters tetrahydrofuran tion University Vmax X-ray yield