Quarterly Journal of the Chemical Society of London, Volume 11 |
From inside the book
Results 1-3 of 45
Page 2232
... peroxide in reflux- ing chloroform . Saponification of the intermediate ( I ; R Me ) gave , after sublimation , 4 - methylcatechol in 65 % yield . Treatment of the sodium salt of p - cresol in ether with benzoyl peroxide at 25 ° gave ...
... peroxide in reflux- ing chloroform . Saponification of the intermediate ( I ; R Me ) gave , after sublimation , 4 - methylcatechol in 65 % yield . Treatment of the sodium salt of p - cresol in ether with benzoyl peroxide at 25 ° gave ...
Page 2282
... peroxide in a series of alkyl benzyl ethers PhCH , OR ( R = Me , Et , Pr1 , But , or Ph ) show little induced decomposition of the peroxide by the ether radical PhCHOR . whereas in the case of the chloro - substituted ethers ArCH , OR ...
... peroxide in a series of alkyl benzyl ethers PhCH , OR ( R = Me , Et , Pr1 , But , or Ph ) show little induced decomposition of the peroxide by the ether radical PhCHOR . whereas in the case of the chloro - substituted ethers ArCH , OR ...
Page 2286
... peroxide was 93 % . 4 - Chlorobenzyl isopropyl ether . The decomposition of t - butyl peroxide in the ether for 96 h gave the following results ( g.l.c. analysis ) : ( a ) peroxide reacted 0.88 mmol ( 82 % ) ( 8 ft in SF - 96 / DC - 550 ...
... peroxide was 93 % . 4 - Chlorobenzyl isopropyl ether . The decomposition of t - butyl peroxide in the ether for 96 h gave the following results ( g.l.c. analysis ) : ( a ) peroxide reacted 0.88 mmol ( 82 % ) ( 8 ft in SF - 96 / DC - 550 ...
Contents
Organic chemistry | 2023 |
Constituents of Withania somnifera Dun Part XII The withanolides of an Indian chemotype | 2032 |
Cyclic hydroxamic acids Part I Synthesis and reactions of 12dihydro1hydroxy46dimethyl2oxo | 2044 |
36 other sections not shown
Other editions - View all
Common terms and phrases
acetic acid acetic anhydride acetone acetyl alcohol aldehyde alumina Amer amine ammonia anhydride anhydrous aqueous aromatic atom benzene benzyl bromide CH₂ Chem chloride chloroform chromatographed cm.¹ cm¯¹ cm¹ compound cooled crystallised cyclisation decomp derivative dichloromethane dilute dimer dimethyl dimethylformamide dioxan dried eluted ester ethanol ethyl acetate evaporated extracted with ether filtered filtrate Found gave give heated under reflux hydrochloric acid hydrolysis hydroxide i.r. spectrum iodide isolated isomer ketone lithium aluminium hydride methyl mixed m.p. mixture was stirred mmHg mmol mmole mole n.m.r. spectrum needles nitrogen obtained olefinic oxidation peroxide phenol potassium prepared protons pyridine reaction reduction reflux requires residue ring room temperature salt signals singlet sodium borohydride sodium hydroxide solid solution solvent spectra structure synthesis tetrahydrofuran treatment yield