Journal of the Chemical SocietyThe Society., 1963 |
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Page 2922
... hydrolysis and theirs was a simultaneous hydrolysis and ethanolysis . They found succinic to be slightly more reactive than glutaric anhydride , and suggested that this difference was due to an inductive effect relayed through two ...
... hydrolysis and theirs was a simultaneous hydrolysis and ethanolysis . They found succinic to be slightly more reactive than glutaric anhydride , and suggested that this difference was due to an inductive effect relayed through two ...
Page 2925
... hydrolysis of amides , 5,10 is much slower than hydrolysis . Exchange is barely detectable during the hydrolyses of acetic and camphoric anhydride , i.e. , kĥ / 2k . > 150. The activation energy for exchange is greater than for hydrolysis ...
... hydrolysis of amides , 5,10 is much slower than hydrolysis . Exchange is barely detectable during the hydrolyses of acetic and camphoric anhydride , i.e. , kĥ / 2k . > 150. The activation energy for exchange is greater than for hydrolysis ...
Page 3131
... hydrolysis of dimethyl selenate is fast and the second slow ; the position is reversed in aqueous dioxan . The two stages will be discussed separately . Hydrolysis of Methyl Hydrogen Selenate . - Addition of dimethyl selenate to water ...
... hydrolysis of dimethyl selenate is fast and the second slow ; the position is reversed in aqueous dioxan . The two stages will be discussed separately . Hydrolysis of Methyl Hydrogen Selenate . - Addition of dimethyl selenate to water ...
Contents
Organic | 2567 |
Gibberellic acid Part XXIII Some perhydrofluoren8aylacetic acid lactones | 2590 |
Gibberellic acid Part XXV Some new reduction products of gibberellic acid | 2606 |
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Common terms and phrases
absorption acetic acid acetic anhydride acetone acetyl alumina Amer amine anhydride atom band benzene benzoate Calc carboxylate catalyst cation CH₂ Chem chloride chloroform chromatography cm.¹ complex compound concentration constant crystallised decomp decomposition derivative dibromide dilute dimethyl dioxan distilled dried eluted ester ethanol ethyl acetate evaporated experimental extracted with ether filtered filtrate flindissone formation Found fraction gave H₂O heated hydrochloric acid hydrogen bromide hydrogen chloride hydrogen peroxide hydrolysis hydroxide infrared infrared spectrum k₁ ketone kinetic lactone light petroleum liquid lithium aluminium hydride mixed m. p. mixture mole mµ ɛ needles nitrogen obtained optical oxidation oxygen petroleum b. p. phenol potassium prepared prisms proton pteridine pyridine pyrolysis reaction reagent refluxed requires residue resin room temperature salt scission sodium hydrogen carbonate sodium hydroxide solvent spectra structure Table thiolactone toluene-p-sulphonic ultraviolet values vinyl Vmax washed yield