Journal of the Chemical Society, Part 2, Pages 1201-2488The Society., 1964 "Titles of chemical papers in British and foreign journals" included in Quarterly journal, v. 1-12. |
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Page 1335
... ( moles 1. - 1 ) 103k1 ( sec . - 1 ) ką ( 1. mole1 sec . - 1 ) . 86.2 109 110 138 215-5 0.922 1.16 1.17 1.46 2.29 0.107 0.106 Average ką == 0.106 0.106 0.1060-002 1. mole - 1 sec . - 1 . 0.106 At 40 ° . At 48 ° . 10 % [ TCVC ] ( moles 1. - 1 ) ...
... ( moles 1. - 1 ) 103k1 ( sec . - 1 ) ką ( 1. mole1 sec . - 1 ) . 86.2 109 110 138 215-5 0.922 1.16 1.17 1.46 2.29 0.107 0.106 Average ką == 0.106 0.106 0.1060-002 1. mole - 1 sec . - 1 . 0.106 At 40 ° . At 48 ° . 10 % [ TCVC ] ( moles 1. - 1 ) ...
Page 1336
... 1. mole - 1 Average k2 sec . - 1 . = 1.150.03 1. mole - 1 sec . - 1 . NN - Dibutylaniline ( DBA ) At 32.5 ° . 10 [ TCVC ] ( moles 1. - 1 ) 0.38 0.76 1.22 1.22 1.51 2.39 ... 10 [ DBA ] ( moles 1. - 1 ) 20.6 8.22 1.09 13.7 27.4 17.2 103k1 ( ...
... 1. mole - 1 Average k2 sec . - 1 . = 1.150.03 1. mole - 1 sec . - 1 . NN - Dibutylaniline ( DBA ) At 32.5 ° . 10 [ TCVC ] ( moles 1. - 1 ) 0.38 0.76 1.22 1.22 1.51 2.39 ... 10 [ DBA ] ( moles 1. - 1 ) 20.6 8.22 1.09 13.7 27.4 17.2 103k1 ( ...
Page 1612
... 1. - 1 , [ H2SO1 ] 1.81 moles 1. - 1 . The salt concentration was adjusted to 0.29 moles 1. - 1 by means of sodium ... mole 1. - 1 sec . - 1 ) 2.72 6.93 13.0 21.0 27.3 38.1 46.5 3.00 6.89 12.1 21.3 26.4 39.7 46.8 ( b ) Dependence of ...
... 1. - 1 , [ H2SO1 ] 1.81 moles 1. - 1 . The salt concentration was adjusted to 0.29 moles 1. - 1 by means of sodium ... mole 1. - 1 sec . - 1 ) 2.72 6.93 13.0 21.0 27.3 38.1 46.5 3.00 6.89 12.1 21.3 26.4 39.7 46.8 ( b ) Dependence of ...
Contents
NO PAGE | 1205 |
The SN mechanism in aromatic compounds Part XXX The sydnone ring | 1213 |
NO PAGE | 1224 |
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1-phenylethyl absorption acetic acid acetone acetonitrile adducts alcohol alginic acid Amer amine aniline aqueous atom benzene bond bromide Calc calculated carbon carboxyl CH₂ Chem chloride chloroform chromatography cm.¹ complex compounds concentration corresponding crystallised derived diazomethane diphenylphosphinic dissociation constants distilled enol equation equilibrium constants ester ethanol ether evaporated experimental extracted fluorine formation formed Found fraction gave H₂O hydrazine hydrides hydrogen cyanide hydrolysis hydroxide infrared spectrum iodide ionisation isomers k₁ k₂ kcal kinetic ligand methanolysis methyl mixed m. p. mixture mmoles mole mole-¹ molecule nitrogen nucleophilic o-complex obtained optical orbitals oxaloacetic acid oxidation oxygen peaks peroxide phenols phosphate phosphine potassium prepared proton pyridine rate coefficients reaction reduced reflux requires residue room temperature rotation shown similar sodium solution solvent spectra structure substituted sulphide sulphuric t-butyl Table tetracyanoethylene titration tricyanovinyl values yield