Quarterly Journal of the Chemical Society of London |
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Page 60
... equation . In the latter case , the carrier is consumed by the amine as fast as the carrier is produced , and so the concentration of amine does not appear in the rate - equation : what is measured now is the rate of a purely inorganic ...
... equation . In the latter case , the carrier is consumed by the amine as fast as the carrier is produced , and so the concentration of amine does not appear in the rate - equation : what is measured now is the rate of a purely inorganic ...
Page 89
... equation ( 1 ) , then less steeply , and finally not at all as a maximum rate is reached , which is given by equation ( 2 ) . Similarly , equations ( 5 ) and ( 6 ) are limiting equations , which bracket a band of transitional kinetic ...
... equation ( 1 ) , then less steeply , and finally not at all as a maximum rate is reached , which is given by equation ( 2 ) . Similarly , equations ( 5 ) and ( 6 ) are limiting equations , which bracket a band of transitional kinetic ...
Page 90
... equation for the preliminary self - dehydration of nitrous acid to form dinitrogen trioxide is equation ( 2 ) , and we measure this inorganic - chemical process when we follow diazotisation kinetics in the form of equation ( 2 ) . The ...
... equation for the preliminary self - dehydration of nitrous acid to form dinitrogen trioxide is equation ( 2 ) , and we measure this inorganic - chemical process when we follow diazotisation kinetics in the form of equation ( 2 ) . The ...
Contents
19 | 4 |
The effect of temperature on azonitriles as initiators in the polymerization of styrene | 12 |
The kinetics and mechanisms of addition to olefinic substances Part V Products | 36 |
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absorption acetic acid acetic anhydride alcohol alkoxides Amer amine ammonia aniline anion aromatic atoms benzene boiling bromine buffer C₁ Calc carbonate catalysed cation Chem chloride chromatography colourless complex compound concentration constant containing crystallised decomp derivative diazotisation dilute dinitrogen trioxide disaccharide dissolved distilled equation ester ethanol ether ethylenediamine evaporated EXPERIMENTAL extracted filtered filtrate formation Found fraction gave give H₂O halides heated hydrochloric acid hydrogen hydrogen chloride hydrolysis hypochlorous iodide ionic isolated isomer K₁ kinetic ligand light petroleum b. p. m. p. and mixed mannose methyl mixed m. p. mixture mole mole-¹ molecular molecule needles niobium nitrate nitrosating nitrosonium nitrous acid obtained oxidation pentafluoride perchloric acid phenylhydrazine potassium precipitate prepared prisms pyridine rate-constants reaction reactivity refluxed requires residue resin salt silver sodium hydroxide solid solvent spectra stoicheiometric sugar sulphuric acid syrup Table values yellow yield