Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 196
... discussion of the mechanism is given in the previous Part.1 RESULTS AND DISCUSSION ortho - Alkyl Substituents . - Values of second - order rate coefficients for the reactions of o - alkylbenzoic acids with diazodiphenylmethane in ...
... discussion of the mechanism is given in the previous Part.1 RESULTS AND DISCUSSION ortho - Alkyl Substituents . - Values of second - order rate coefficients for the reactions of o - alkylbenzoic acids with diazodiphenylmethane in ...
Page 257
... Discussion ) . DISCUSSION The Deviation from First - order in Copper Chloride .-- Equation ( 6 ) implies that when [ CuCl2 ] is no longer negligible , the overall reaction will become slower , and deviate from first - order in copper ...
... Discussion ) . DISCUSSION The Deviation from First - order in Copper Chloride .-- Equation ( 6 ) implies that when [ CuCl2 ] is no longer negligible , the overall reaction will become slower , and deviate from first - order in copper ...
Page 309
... discussion . In fact , as for oxazole and isoxazole , 11 the product rule for a class containing 13 normal modes ( A ' ) can give ambiguous results , since different choices are possible which satisfy it with the same , or nearly the ...
... discussion . In fact , as for oxazole and isoxazole , 11 the product rule for a class containing 13 normal modes ( A ' ) can give ambiguous results , since different choices are possible which satisfy it with the same , or nearly the ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
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absorption acetic acid Acta alcohol alkyl Amer amine angles anion aqueous aromatic ation benzene bond bromide calculated carbanion carbon tetrachloride CH₂ Chem chemical shifts Chemistry Chim chloride CO₂H compounds concentration conformation corresponding coupling constants decomposition derived di-imine dioxan dipole effect electron equation esters ethanol ether experimental Figure first-order fluorine formation formed hydrogen hydrolysis hydroxide hypochlorous acid interaction intermediate iodide irradiation isomer isomerisation isopropyl k₁ ketone kinetic measured mechanism mercuric mesitylene method methyl mixture mole mole-¹ molecular molecule n.m.r. spectra nitration nitrogen observed obtained olefin oxidation oxygen peaks peroxide phenyl Phys plot polymer proton radical rate constants ratio reactants reaction reactivity reduced relative resonance ring salts showed shown similar singlet sodium solution solvent solvolysis spectrum steric steric effect structure substituent sulphoxide t-butyl Table temperature titanium(III triethyl phosphite values