Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 74
... addition of bromobenzene . It is well known that autoxidations of methylbenzenes catalysed by cobalt ( 11 ) acetate in acetic acid are acceler- ated by the addition of substances giving rise to bromide ions such as hydrogen bromide ...
... addition of bromobenzene . It is well known that autoxidations of methylbenzenes catalysed by cobalt ( 11 ) acetate in acetic acid are acceler- ated by the addition of substances giving rise to bromide ions such as hydrogen bromide ...
Page 140
... addition of bromotrichloro- methane to oct - 1 - ene , a smaller yield being obtained from the corresponding ... addition of t - butylcatechol ( 2 % ) did not alter the rate profile ( Figure 5 ) while the addition of AIBN ( 1-2 ...
... addition of bromotrichloro- methane to oct - 1 - ene , a smaller yield being obtained from the corresponding ... addition of t - butylcatechol ( 2 % ) did not alter the rate profile ( Figure 5 ) while the addition of AIBN ( 1-2 ...
Page 255
... addition of styrene to aromatic sulphonyl chlorides which carry substituents with a wide range of Hammetto - values , has been studied by dilatometry at 110 ° with acetonitrile as the solvent . When an excess of styrene is used , the ...
... addition of styrene to aromatic sulphonyl chlorides which carry substituents with a wide range of Hammetto - values , has been studied by dilatometry at 110 ° with acetonitrile as the solvent . When an excess of styrene is used , the ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
Copyright | |
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absorption acetic acid Acta alcohol alkyl Amer amine angles anion aqueous aromatic ation benzene bond bromide calculated carbon tetrachloride CH₂ Chem chemical shifts Chemistry Chim chloride CO₂H coefficients compounds concentration conformation corresponding coupling constants decomposition derived di-imine dioxan dipole effect electron equation esters ethanol ether experimental Figure first-order fluorine formation formed hydrogen hydrolysis hydroxide hypochlorous acid interaction intermediate iodide irradiation isomer isomerisation isopropyl k₁ ketone kinetic measured mechanism mercuric mesitylene method methyl mixture mole mole-¹ molecular molecule n.m.r. spectra nitration nitrogen observed obtained olefin oxidation oxygen peaks peroxide phenyl Phys plot polymer proton radical rate constants ratio reactants reaction reactivity reduced relative resonance ring salts showed shown similar singlet sodium solution solvent solvolysis spectrum steric steric effect structure substituent sulphoxide t-butyl Table temperature titanium(III triethyl phosphite values