Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 145
... alcohol was detected by g.l.c. , preliminary calibration having shown that the limit of detection of pinacolyl alcohol was less than 1 % of that theoretically possible on the assumption of a rate constant k1 of 3.7 x 103 min . - 1 ...
... alcohol was detected by g.l.c. , preliminary calibration having shown that the limit of detection of pinacolyl alcohol was less than 1 % of that theoretically possible on the assumption of a rate constant k1 of 3.7 x 103 min . - 1 ...
Page 396
... alcohol , formaldehyde , and acetaldehyde ) belong to this category , for the derived radicals have been shown in other ways to be good one - electron reducing agents 19,20,26 ( with the two aldehydes , the reducing agents are evi ...
... alcohol , formaldehyde , and acetaldehyde ) belong to this category , for the derived radicals have been shown in other ways to be good one - electron reducing agents 19,20,26 ( with the two aldehydes , the reducing agents are evi ...
Page 410
... alcohols or dioxan . However , when [ PhN2 + ] / k4 and [ R • ] = [ Ph • ] ( k2 [ RH ] / kg [ PhN2 * ] ) . If isopropyl alcohol was included , the intensity of dimerisation is diffusion - controlled , k 1010 1. mole- the spectrum of the ...
... alcohols or dioxan . However , when [ PhN2 + ] / k4 and [ R • ] = [ Ph • ] ( k2 [ RH ] / kg [ PhN2 * ] ) . If isopropyl alcohol was included , the intensity of dimerisation is diffusion - controlled , k 1010 1. mole- the spectrum of the ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
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absorption acetic acid Acta alcohol alkyl Amer amine angles anion aqueous aromatic ation benzene bond bromide calculated carbon tetrachloride CH₂ Chem chemical shifts Chemistry Chim chloride CO₂H coefficients compounds concentration conformation corresponding coupling constants decomposition derived di-imine dioxan dipole effect electron equation esters ethanol ether experimental Figure first-order fluorine formation formed hydrogen hydrolysis hydroxide hypochlorous acid interaction intermediate iodide irradiation isomer isomerisation isopropyl k₁ ketone kinetic measured mechanism mercuric mesitylene method methyl mixture mole mole-¹ molecular molecule n.m.r. spectra nitration nitrogen observed obtained olefin oxidation oxygen peaks peroxide phenyl Phys plot polymer proton radical rate constants ratio reactants reaction reactivity reduced relative resonance ring salts showed shown similar singlet sodium solution solvent solvolysis spectrum steric steric effect structure substituent sulphoxide t-butyl Table temperature titanium(III triethyl phosphite values