Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 229
... Calculations of Theoretical Molar Kerr Constants.— Theoretical Kerr constants have been calculated by addition of bond polarisability tensors using routine TABLE 4 Dipole moment directions in the benzoylanthracenes Molecule 9 - Bz 2.89 ...
... Calculations of Theoretical Molar Kerr Constants.— Theoretical Kerr constants have been calculated by addition of bond polarisability tensors using routine TABLE 4 Dipole moment directions in the benzoylanthracenes Molecule 9 - Bz 2.89 ...
Page 230
... calculations described above . However , in view of the difficulty with 9 - benzoyl- 10 - cyanoanthracene , it was of interest to examine the effect of such exaltation on our conclusions . The values of Ab were calculated as where ( bi ) ...
... calculations described above . However , in view of the difficulty with 9 - benzoyl- 10 - cyanoanthracene , it was of interest to examine the effect of such exaltation on our conclusions . The values of Ab were calculated as where ( bi ) ...
Page 487
... calculated from a TABLE 4 Calculated dipole moments and molar Kerr constants for uniplanar conformations of 1,4 - diacetylbenzene Structure ( I ) ( cis ) ( II ) ( trans ) TABLE 5 μ ( D ) 5.02 m 1012 K +1173 +31 observed moment by use of ...
... calculated from a TABLE 4 Calculated dipole moments and molar Kerr constants for uniplanar conformations of 1,4 - diacetylbenzene Structure ( I ) ( cis ) ( II ) ( trans ) TABLE 5 μ ( D ) 5.02 m 1012 K +1173 +31 observed moment by use of ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
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absorption acetic acid Acta alcohol alkyl Amer amine angles anion aqueous aromatic ation benzene bond bromide calculated carbanion carbon tetrachloride CH₂ Chem chemical shifts Chemistry Chim chloride CO₂H compounds concentration conformation corresponding coupling constants decomposition derived di-imine dioxan dipole effect electron equation esters ethanol ether experimental Figure first-order fluorine formation formed hydrogen hydrolysis hydroxide hypochlorous acid interaction intermediate iodide irradiation isomer isomerisation isopropyl k₁ ketone kinetic measured mechanism mercuric mesitylene method methyl mixture mole mole-¹ molecular molecule n.m.r. spectra nitration nitrogen observed obtained olefin oxidation oxygen peaks peroxide phenyl Phys plot polymer proton radical rate constants ratio reactants reaction reactivity reduced relative resonance ring salts showed shown similar singlet sodium solution solvent solvolysis spectrum steric steric effect structure substituent sulphoxide t-butyl Table temperature titanium(III triethyl phosphite values