Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 229
... Calculations of Theoretical Molar Kerr Constants.— Theoretical Kerr constants have been calculated by addition of bond polarisability tensors using routine TABLE 4 Dipole moment directions in the benzoylanthracenes Molecule 9 - Bz 2.89 ...
... Calculations of Theoretical Molar Kerr Constants.— Theoretical Kerr constants have been calculated by addition of bond polarisability tensors using routine TABLE 4 Dipole moment directions in the benzoylanthracenes Molecule 9 - Bz 2.89 ...
Page 230
... calculations described above . However , in view of the difficulty with 9 - benzoyl- 10 - cyanoanthracene , it was of interest to examine the effect of such exaltation on our conclusions . The values of Ab were calculated as where ( bi ) ...
... calculations described above . However , in view of the difficulty with 9 - benzoyl- 10 - cyanoanthracene , it was of interest to examine the effect of such exaltation on our conclusions . The values of Ab were calculated as where ( bi ) ...
Page 487
... calculated from a TABLE 4 Calculated dipole moments and molar Kerr constants for uniplanar conformations of 1,4 - diacetylbenzene Structure ( I ) ( cis ) ( II ) ( trans ) TABLE 5 μ ( D ) 5.02 m 1012 K +1173 +31 observed moment by use of ...
... calculated from a TABLE 4 Calculated dipole moments and molar Kerr constants for uniplanar conformations of 1,4 - diacetylbenzene Structure ( I ) ( cis ) ( II ) ( trans ) TABLE 5 μ ( D ) 5.02 m 1012 K +1173 +31 observed moment by use of ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
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absorption acetic acid activation added addition alcohol Amer analysis angles appears aqueous atom base benzene bond bromide calculated carbon carbon tetrachloride Chem chemical chloride compared complex compounds concentration conformation constants containing corresponding coupling derived described determined DISCUSSION effect electron energy equation esters ethanol ether expected experimental experiments factor Figure followed formation formed further gave give given hydrogen hydrolysis increase indicate initial intermediate involving kinetic less measured mechanism method methyl mixing mixture mole molecular molecule nitration observed obtained occurs organic oxidation oxygen peaks peroxide Phys plot position possible prepared present pressure proton radical rate constants ratio reaction reactivity reduced relative reported requires resonance respectively ring salts shifts showed shown similar sodium solution solvent spectra spectrum structure studied substituent suggested Table temperature values yield