Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 138
... Carbon Tetrachloride and Bromotrichloro- methane in the Presence and Absence of Butane - 1 - thiol By R. E. Atkinson , J. I. G. Cadogan , * and J. T. Sharp , Department of Chemistry , University of St. Andrews , St. Andrews , Scotland ...
... Carbon Tetrachloride and Bromotrichloro- methane in the Presence and Absence of Butane - 1 - thiol By R. E. Atkinson , J. I. G. Cadogan , * and J. T. Sharp , Department of Chemistry , University of St. Andrews , St. Andrews , Scotland ...
Page 427
Chemical Society (Great Britain). Solvents . - Carbon tetrachloride was fractionated and dried ( CaCl , ) ; benzene was fractionally crystallised , dis- tilled , and dried over sodium . The following data apply at 25 ° : Carbon ...
Chemical Society (Great Britain). Solvents . - Carbon tetrachloride was fractionated and dried ( CaCl , ) ; benzene was fractionally crystallised , dis- tilled , and dried over sodium . The following data apply at 25 ° : Carbon ...
Page 436
... carbon to nitrogen . By combining this with the values calculated for the effect of F , Cl , or OH on an attached carbon atom derived by using orbital electronegativities in the manner described previously , gives aoc ( x ) values for ...
... carbon to nitrogen . By combining this with the values calculated for the effect of F , Cl , or OH on an attached carbon atom derived by using orbital electronegativities in the manner described previously , gives aoc ( x ) values for ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
Copyright | |
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absorption acetic acid Acta alcohol alkyl Amer amine angles anion aqueous aromatic ation benzene bond bromide calculated carbon tetrachloride CH₂ Chem chemical shifts Chemistry Chim chloride CO₂H coefficients compounds concentration conformation corresponding coupling constants decomposition derived di-imine dioxan dipole effect electron equation esters ethanol ether experimental Figure first-order fluorine formation formed hydrogen hydrolysis hydroxide hypochlorous acid interaction intermediate iodide irradiation isomer isomerisation isopropyl k₁ ketone kinetic measured mechanism mercuric mesitylene method methyl mixture mole mole-¹ molecular molecule n.m.r. spectra nitration nitrogen observed obtained olefin oxidation oxygen peaks peroxide phenyl Phys plot polymer proton radical rate constants ratio reactants reaction reactivity reduced relative resonance ring salts showed shown similar singlet sodium solution solvent solvolysis spectrum steric steric effect structure substituent sulphoxide t-butyl Table temperature titanium(III triethyl phosphite values