Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 138
... Carbon Tetrachloride and Bromotrichloro- methane in the Presence and Absence of Butane - 1 - thiol By R. E. Atkinson , J. I. G. Cadogan , * and J. T. Sharp , Department of Chemistry , University of St. Andrews , St. Andrews , Scotland ...
... Carbon Tetrachloride and Bromotrichloro- methane in the Presence and Absence of Butane - 1 - thiol By R. E. Atkinson , J. I. G. Cadogan , * and J. T. Sharp , Department of Chemistry , University of St. Andrews , St. Andrews , Scotland ...
Page 427
Chemical Society (Great Britain). Solvents . - Carbon tetrachloride was fractionated and dried ( CaCl , ) ; benzene was fractionally crystallised , dis- tilled , and dried over sodium . The following data apply at 25 ° : Carbon ...
Chemical Society (Great Britain). Solvents . - Carbon tetrachloride was fractionated and dried ( CaCl , ) ; benzene was fractionally crystallised , dis- tilled , and dried over sodium . The following data apply at 25 ° : Carbon ...
Page 436
... carbon to nitrogen . By combining this with the values calculated for the effect of F , Cl , or OH on an attached carbon atom derived by using orbital electronegativities in the manner described previously , gives aoc ( x ) values for ...
... carbon to nitrogen . By combining this with the values calculated for the effect of F , Cl , or OH on an attached carbon atom derived by using orbital electronegativities in the manner described previously , gives aoc ( x ) values for ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
Copyright | |
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absorption acetic acid activation added addition alcohol Amer analysis angles appears aqueous atom base benzene bond bromide calculated carbon carbon tetrachloride Chem chemical chloride compared complex compounds concentration conformation constants containing corresponding coupling derived described determined DISCUSSION effect electron energy equation esters ethanol ether expected experimental experiments factor Figure followed formation formed further gave give given hydrogen hydrolysis increase indicate initial intermediate involving kinetic less measured mechanism method methyl mixing mixture mole molecular molecule nitration observed obtained occurs organic oxidation oxygen peaks peroxide Phys plot position possible prepared present pressure proton radical rate constants ratio reaction reactivity reduced relative reported requires resonance respectively ring salts shifts showed shown similar sodium solution solvent spectra spectrum structure studied substituent suggested Table temperature values yield