Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 74
... concentration of toluene , i.e. two with 0.5M - toluene and four with 2M - toluene . Differ- ent toluene concentrations gave nearly the same absorp- tion curve below 50 % conversion ; thus the rate is independent of the toluene ...
... concentration of toluene , i.e. two with 0.5M - toluene and four with 2M - toluene . Differ- ent toluene concentrations gave nearly the same absorp- tion curve below 50 % conversion ; thus the rate is independent of the toluene ...
Page 75
... concentration at constant concentrations of toluene ( 0-8059м ) and bromobenzene ( 1.0422м ) at 90 ° ; catalyst concentrations : ( — O — ) 0 · 1241м , ( —— ) 0.1862M , ( x ) 0.2482M times . A rapid decrease in the concentration of benz ...
... concentration at constant concentrations of toluene ( 0-8059м ) and bromobenzene ( 1.0422м ) at 90 ° ; catalyst concentrations : ( — O — ) 0 · 1241м , ( —— ) 0.1862M , ( x ) 0.2482M times . A rapid decrease in the concentration of benz ...
Page 99
... concentration [ NaOH ] ( M ) : 0.05 0.20 103k , ( min . - 1 ) * The values of k1 are approximate , because the complete dissolution of the amines at these concentrations is uncertain . TABLE 13 Deamination of the 9 - aminoacridines at ...
... concentration [ NaOH ] ( M ) : 0.05 0.20 103k , ( min . - 1 ) * The values of k1 are approximate , because the complete dissolution of the amines at these concentrations is uncertain . TABLE 13 Deamination of the 9 - aminoacridines at ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
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absorption acetic acid activation added addition alcohol Amer analysis angles appears aqueous atom base benzene bond bromide calculated carbon carbon tetrachloride Chem chemical chloride compared complex compounds concentration conformation constants containing corresponding coupling derived described determined DISCUSSION effect electron energy equation esters ethanol ether expected experimental experiments factor Figure followed formation formed further gave give given hydrogen hydrolysis increase indicate initial intermediate involving kinetic less measured mechanism method methyl mixing mixture mole molecular molecule nitration observed obtained occurs organic oxidation oxygen peaks peroxide Phys plot position possible prepared present pressure proton radical rate constants ratio reaction reactivity reduced relative reported requires resonance respectively ring salts shifts showed shown similar sodium solution solvent spectra spectrum structure studied substituent suggested Table temperature values yield