Quarterly Journal of the Chemical Society of London, Volume 1 |
From inside the book
Results 1-3 of 83
Page 178
... constants . Experiments performed over a range of temperatures have yielded values for AG , AH , and AS . An equation has been derived which permits the calculation of mutarotation constants from the dissociation constants and the pH at ...
... constants . Experiments performed over a range of temperatures have yielded values for AG , AH , and AS . An equation has been derived which permits the calculation of mutarotation constants from the dissociation constants and the pH at ...
Page 253
... constants have been found : Jax ± 9.92 , J'ax ± 7 · 12 , J △△ ± 9.36 , Jxx ± 0 · 10 , J'xx ± 14 · 03 , and J'xx ± 3.01 c./sec . Assignments of these coupling constants are discussed . Redox - transfer . Part VI.1 Determination of ...
... constants have been found : Jax ± 9.92 , J'ax ± 7 · 12 , J △△ ± 9.36 , Jxx ± 0 · 10 , J'xx ± 14 · 03 , and J'xx ± 3.01 c./sec . Assignments of these coupling constants are discussed . Redox - transfer . Part VI.1 Determination of ...
Page 428
... constants calculated from Table 1 * Calculating assuming DP TABLE 7 Dipole moments and molar Kerr constants for conformations. ∞ P2 Solute Solvent αει β y'n2 , ( cm.3 ) RD ( cm.3 ) μ ( D ) γ 8 1012∞ ( K2 ) 1 - Chloroanthracene CCI 3.05 ...
... constants calculated from Table 1 * Calculating assuming DP TABLE 7 Dipole moments and molar Kerr constants for conformations. ∞ P2 Solute Solvent αει β y'n2 , ( cm.3 ) RD ( cm.3 ) μ ( D ) γ 8 1012∞ ( K2 ) 1 - Chloroanthracene CCI 3.05 ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
Copyright | |
6 other sections not shown
Other editions - View all
Common terms and phrases
absorption acetic acid Acta alcohol alkyl Amer amine angles anion aqueous aromatic ation benzene bond bromide calculated carbanion carbon tetrachloride CH₂ Chem chemical shifts Chemistry Chim chloride CO₂H compounds concentration conformation corresponding coupling constants decomposition derived di-imine dioxan dipole effect electron equation esters ethanol ether experimental Figure first-order formation formed H₂O hydrogen hydrolysis hydroxide hypochlorous acid interaction intermediate iodide irradiation isomer isomerisation isopropyl k₁ ketone kinetic measured mercuric mesitylene method methyl mixture mole mole-¹ molecular molecule n.m.r. spectra nitration nitrogen observed obtained olefin oxidation oxygen peaks peroxide phenyl Phys plot polymer proton radical rate constants ratio reactants reaction reactivity reduced relative resonance ring salts showed shown similar singlet sodium sodium hydroxide solution solvent solvolysis spectrum steric steric effect structure substituent sulphoxide t-butyl Table temperature titanium(III triethyl phosphite values