Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 121
... described in Part III . Benzoyl peroxide ( 2 g . ) was allowed to decompose in 50 , 100 , and 400 ml . of fluorobenzene for 72 hr . at 80-2 ° and the following scheme of analysis was adopted throughout . ( i ) Benzoic acid was extracted ...
... described in Part III . Benzoyl peroxide ( 2 g . ) was allowed to decompose in 50 , 100 , and 400 ml . of fluorobenzene for 72 hr . at 80-2 ° and the following scheme of analysis was adopted throughout . ( i ) Benzoic acid was extracted ...
Page 246
... described in ( a ) , bromo- vinyl ketone ( Ib ) ( 0.24 g . , 1 x 10-3 mole ) and sodium benzenethiolate ( 0.176 g . , 1.3 x 10-3 mole ) gave cis- sulphide ( III ) ( 0 · 23 g . , 85 % ) , m.p. 107-108 ° ( from ethanol ) . ( c ) From ...
... described in ( a ) , bromo- vinyl ketone ( Ib ) ( 0.24 g . , 1 x 10-3 mole ) and sodium benzenethiolate ( 0.176 g . , 1.3 x 10-3 mole ) gave cis- sulphide ( III ) ( 0 · 23 g . , 85 % ) , m.p. 107-108 ° ( from ethanol ) . ( c ) From ...
Page 474
... described in this paper . Obtained by the corresponding bromo - derivatives with cuprous cyanide , ' as described in Part II.1 By refluxing the corresponding nitriles with 30 % sodium hydroxide and methanol for 72 hr . , as described in ...
... described in this paper . Obtained by the corresponding bromo - derivatives with cuprous cyanide , ' as described in Part II.1 By refluxing the corresponding nitriles with 30 % sodium hydroxide and methanol for 72 hr . , as described in ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
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absorption acetic acid Acta alcohol alkyl Amer amine angles anion aqueous aromatic ation benzene bond bromide calculated carbon tetrachloride CH₂ Chem chemical shifts Chemistry Chim chloride CO₂H coefficients compounds concentration conformation corresponding coupling constants decomposition derived di-imine dioxan dipole effect electron equation esters ethanol ether experimental Figure first-order fluorine formation formed hydrogen hydrolysis hydroxide hypochlorous acid interaction intermediate iodide irradiation isomer isomerisation isopropyl k₁ ketone kinetic measured mechanism mercuric mesitylene method methyl mixture mole mole-¹ molecular molecule n.m.r. spectra nitration nitrogen observed obtained olefin oxidation oxygen peaks peroxide phenyl Phys plot polymer proton radical rate constants ratio reactants reaction reactivity reduced relative resonance ring salts showed shown similar singlet sodium solution solvent solvolysis spectrum steric steric effect structure substituent sulphoxide t-butyl Table temperature titanium(III triethyl phosphite values