Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 130
... [ Ester ] / dt = ( k1 [ Ester ] [ Amine ] + k2 [ Ester ] [ Amine ] 2 ) . In acetonitrile solution this equation is simplified to d [ Ester ] / dt = k1 [ Ester ] [ Amine ] . The aminolysis of esters of the form R1CO • O • NR2 , obeys the ...
... [ Ester ] / dt = ( k1 [ Ester ] [ Amine ] + k2 [ Ester ] [ Amine ] 2 ) . In acetonitrile solution this equation is simplified to d [ Ester ] / dt = k1 [ Ester ] [ Amine ] . The aminolysis of esters of the form R1CO • O • NR2 , obeys the ...
Page 131
... ester was recrystallised to constant m.p. Prepared by this method the esters p , p ' - R • C ̧H ̧ · CO2 · C ̧HNO , where R = NO2 , C1 , H , CH ,, and MeO had m.p. 158 ° , 144 ° , 144 ° , 124 ° , and 167 ° respectively , while the esters ...
... ester was recrystallised to constant m.p. Prepared by this method the esters p , p ' - R • C ̧H ̧ · CO2 · C ̧HNO , where R = NO2 , C1 , H , CH ,, and MeO had m.p. 158 ° , 144 ° , 144 ° , 124 ° , and 167 ° respectively , while the esters ...
Page 137
... esters R1CONR2 , we consider the mechanism of catalysis to be somewhat different . The great sensitivity of these CH1 • R2 - p RIC - 03 H R3 - N ( V ) H R3 R4 esters to acid catalysis doubtless arises from the special nature of their ...
... esters R1CONR2 , we consider the mechanism of catalysis to be somewhat different . The great sensitivity of these CH1 • R2 - p RIC - 03 H R3 - N ( V ) H R3 R4 esters to acid catalysis doubtless arises from the special nature of their ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
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absorption acetic acid Acta alcohol alkyl Amer amine angles anion aqueous aromatic ation benzene bond bromide calculated carbon tetrachloride CH₂ Chem chemical shifts Chemistry Chim chloride CO₂H coefficients compounds concentration conformation corresponding coupling constants decomposition derived di-imine dioxan dipole effect electron equation esters ethanol ether experimental Figure first-order fluorine formation formed hydrogen hydrolysis hydroxide hypochlorous acid interaction intermediate iodide irradiation isomer isomerisation isopropyl k₁ ketone kinetic measured mechanism mercuric mesitylene method methyl mixture mole mole-¹ molecular molecule n.m.r. spectra nitration nitrogen observed obtained olefin oxidation oxygen peaks peroxide phenyl Phys plot polymer proton radical rate constants ratio reactants reaction reactivity reduced relative resonance ring salts showed shown similar singlet sodium solution solvent solvolysis spectrum steric steric effect structure substituent sulphoxide t-butyl Table temperature titanium(III triethyl phosphite values