Quarterly Journal of the Chemical Society of London, Volume 1 |
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Results 1-3 of 89
Page 392
... experiments ( i ) - ( iii ) is the direct reaction , R + R'H → RH + R ' • . Further , the magnitudes of the effects noted in the three experiments are qualitatively in accord with expectation . Thus , we should expect the radical CH2 ...
... experiments ( i ) - ( iii ) is the direct reaction , R + R'H → RH + R ' • . Further , the magnitudes of the effects noted in the three experiments are qualitatively in accord with expectation . Thus , we should expect the radical CH2 ...
Page 393
... experiments ( iv ) and ( v ) ] . Then , The intervention of reaction ( 1 ) is even more clearly demonstrated by comparison of experiments ( iii ) and ( vi ) . The former experiment shows that the radical • CMeOH is relatively ...
... experiments ( iv ) and ( v ) ] . Then , The intervention of reaction ( 1 ) is even more clearly demonstrated by comparison of experiments ( iii ) and ( vi ) . The former experiment shows that the radical • CMeOH is relatively ...
Page 509
... experiments are used to facilitate the complete analysis of the n.m.r. spectra of CFZ ( Z = CHO , CH , and CF3 ) . An accurate relation is presented between the 1 ° F and 1H resonant frequencies in CF and tetramethylsilane respectively ...
... experiments are used to facilitate the complete analysis of the n.m.r. spectra of CFZ ( Z = CHO , CH , and CF3 ) . An accurate relation is presented between the 1 ° F and 1H resonant frequencies in CF and tetramethylsilane respectively ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
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absorption acetic acid Acta alcohol alkyl Amer amine angles anion aqueous aromatic ation benzene bond bromide calculated carbanion carbon tetrachloride CH₂ Chem chemical shifts Chemistry Chim chloride CO₂H compounds concentration conformation corresponding coupling constants decomposition derived di-imine dioxan dipole effect electron equation esters ethanol ether experimental Figure first-order formation formed H₂O hydrogen hydrolysis hydroxide hypochlorous acid interaction intermediate iodide irradiation isomer isomerisation isopropyl k₁ ketone kinetic measured mercuric mesitylene method methyl mixture mole mole-¹ molecular molecule n.m.r. spectra nitration nitrogen observed obtained olefin oxidation oxygen peaks peroxide phenyl Phys plot polymer proton radical rate constants ratio reactants reaction reactivity reduced relative resonance ring salts showed shown similar singlet sodium sodium hydroxide solution solvent solvolysis spectrum steric steric effect structure substituent sulphoxide t-butyl Table temperature titanium(III triethyl phosphite values