Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 51
... first - order ; plots of log ( pressure of reactant ) against time were linear for as long as they were followed , which was to at least 50 % and in some cases to 85 % isomeris- ation . In agreement with the first - order nature of the ...
... first - order ; plots of log ( pressure of reactant ) against time were linear for as long as they were followed , which was to at least 50 % and in some cases to 85 % isomeris- ation . In agreement with the first - order nature of the ...
Page 257
... first - order reaction in sulphonyl chloride , is valid up to at least 70 % conversion . TABLE 1 Rate constants for the oxidation of cuprous chloride by sulphonylchlorides * Hammett's equation holds very well for this type of reaction ...
... first - order reaction in sulphonyl chloride , is valid up to at least 70 % conversion . TABLE 1 Rate constants for the oxidation of cuprous chloride by sulphonylchlorides * Hammett's equation holds very well for this type of reaction ...
Page 424
... order component in olefin in the rate equation ) into this result . In the absence of any other experi- mental data it will therefore be assumed that the re- action is first order in olefin . The full rate equation then becomes : rate ...
... order component in olefin in the rate equation ) into this result . In the absence of any other experi- mental data it will therefore be assumed that the re- action is first order in olefin . The full rate equation then becomes : rate ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
Copyright | |
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absorption acetic acid Acta alcohol alkyl Amer amine angles anion aqueous aromatic ation benzene bond bromide calculated carbanion carbon tetrachloride CH₂ Chem chemical shifts Chemistry Chim chloride CO₂H compounds concentration conformation corresponding coupling constants decomposition derived di-imine dioxan dipole effect electron equation esters ethanol ether experimental Figure first-order formation formed H₂O hydrogen hydrolysis hydroxide hypochlorous acid interaction intermediate iodide irradiation isomer isomerisation isopropyl k₁ ketone kinetic measured mercuric mesitylene method methyl mixture mole mole-¹ molecular molecule n.m.r. spectra nitration nitrogen observed obtained olefin oxidation oxygen peaks peroxide phenyl Phys plot polymer proton radical rate constants ratio reactants reaction reactivity reduced relative resonance ring salts showed shown similar singlet sodium sodium hydroxide solution solvent solvolysis spectrum steric steric effect structure substituent sulphoxide t-butyl Table temperature titanium(III triethyl phosphite values