Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 100
... increase with the sodium hydroxide concentration ( Table 9 ) more than expected from the hydroxide concentration ... increase with the concentration of potassium hydroxide . They increase from 1.39 , 1.86 , 1.62 , 1 · 34 , 2.11 , and ...
... increase with the sodium hydroxide concentration ( Table 9 ) more than expected from the hydroxide concentration ... increase with the concentration of potassium hydroxide . They increase from 1.39 , 1.86 , 1.62 , 1 · 34 , 2.11 , and ...
Page 307
... increase in temperature caused a slight but significant increase in the rate of both the mercury - sensitised and the direct photolysis of hydrogen sulphide , so that increased temperature would cause an increase in the rate of the ...
... increase in temperature caused a slight but significant increase in the rate of both the mercury - sensitised and the direct photolysis of hydrogen sulphide , so that increased temperature would cause an increase in the rate of the ...
Page 585
... increased with increasing size of alkyl group . This rate increase was attributed to a reduction in conformations ( 14 ) and an increase in conformations ( 15 ) , due to steric interactions . Increase in the size of the alkyl group thus ...
... increased with increasing size of alkyl group . This rate increase was attributed to a reduction in conformations ( 14 ) and an increase in conformations ( 15 ) , due to steric interactions . Increase in the size of the alkyl group thus ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
Copyright | |
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absorption acetic acid Acta alcohol alkyl Amer amine angles anion aqueous aromatic ation benzene bond bromide calculated carbon tetrachloride CH₂ Chem chemical shifts Chemistry Chim chloride CO₂H coefficients compounds concentration conformation corresponding coupling constants decomposition derived di-imine dioxan dipole effect electron equation esters ethanol ether experimental Figure first-order fluorine formation formed hydrogen hydrolysis hydroxide hypochlorous acid interaction intermediate iodide irradiation isomer isomerisation isopropyl k₁ ketone kinetic measured mechanism mercuric mesitylene method methyl mixture mole mole-¹ molecular molecule n.m.r. spectra nitration nitrogen observed obtained olefin oxidation oxygen peaks peroxide phenyl Phys plot polymer proton radical rate constants ratio reactants reaction reactivity reduced relative resonance ring salts showed shown similar singlet sodium solution solvent solvolysis spectrum steric steric effect structure substituent sulphoxide t-butyl Table temperature titanium(III triethyl phosphite values