Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 9
... kinetic From com- measure- petition ments in 7.5 % experi- ments Compound nitrated aqueous in From kinetic measure- ments in 15 % aqueous nitro- From From com- sulpholan sulpholan methane Fluorobenzene 0.091 From petition kinetic experi ...
... kinetic From com- measure- petition ments in 7.5 % experi- ments Compound nitrated aqueous in From kinetic measure- ments in 15 % aqueous nitro- From From com- sulpholan sulpholan methane Fluorobenzene 0.091 From petition kinetic experi ...
Page 283
... kinetic order in mercurial affect the overall reaction at higher reactant concentrations than those illustrated . From the kinetic equation it follows that the rate constant should remain the same when the mercuric TABLE 13 First ...
... kinetic order in mercurial affect the overall reaction at higher reactant concentrations than those illustrated . From the kinetic equation it follows that the rate constant should remain the same when the mercuric TABLE 13 First ...
Page 334
... Kinetic results " for the reactions of alkylthio- , alkyl- sulphinyl- , and alkylsulphonyl - quinoxalines with methoxide ions The results of kinetic studies are given in Tables 1—3 , and the results of preparative experiments in Table 4 ...
... Kinetic results " for the reactions of alkylthio- , alkyl- sulphinyl- , and alkylsulphonyl - quinoxalines with methoxide ions The results of kinetic studies are given in Tables 1—3 , and the results of preparative experiments in Table 4 ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
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absorption acetic acid activation added addition alcohol Amer analysis angles appears aqueous atom base benzene bond bromide calculated carbon carbon tetrachloride Chem chemical chloride compared complex compounds concentration conformation constants containing corresponding coupling derived described determined DISCUSSION effect electron energy equation esters ethanol ether expected experimental experiments factor Figure followed formation formed further gave give given hydrogen hydrolysis increase indicate initial intermediate involving kinetic less measured mechanism method methyl mixing mixture mole molecular molecule nitration observed obtained occurs organic oxidation oxygen peaks peroxide Phys plot position possible prepared present pressure proton radical rate constants ratio reaction reactivity reduced relative reported requires resonance respectively ring salts shifts showed shown similar sodium solution solvent spectra spectrum structure studied substituent suggested Table temperature values yield