Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 1
... nitration has been observed . By adding water to sulpholan and to nitromethane it was possible to produce media in which all the compounds examined were nitrated according to the first - order law ; rates relative to that of benzene ...
... nitration has been observed . By adding water to sulpholan and to nitromethane it was possible to produce media in which all the compounds examined were nitrated according to the first - order law ; rates relative to that of benzene ...
Page 5
... nitration of benzene in sulpholan resembles the corresponding reaction in acetic acid but not that ( zeroth order ) in nitromethane.36 ( b ) First - order nitrations . Whilst the rate of nitration of mesitylene was depressed by the ...
... nitration of benzene in sulpholan resembles the corresponding reaction in acetic acid but not that ( zeroth order ) in nitromethane.36 ( b ) First - order nitrations . Whilst the rate of nitration of mesitylene was depressed by the ...
Page 6
... nitration solutions to ~ 1—2 × 101м . Even so , with very reactive compounds this is sufficient to cause an incursion of the special mechanism mentioned above . The observed rate of nitration of 1 - methylnaphthalene in sulpholan ...
... nitration solutions to ~ 1—2 × 101м . Even so , with very reactive compounds this is sufficient to cause an incursion of the special mechanism mentioned above . The observed rate of nitration of 1 - methylnaphthalene in sulpholan ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
Copyright | |
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absorption acetic acid activation added addition alcohol Amer analysis angles appears aqueous atom base benzene bond bromide calculated carbon carbon tetrachloride Chem chemical chloride compared complex compounds concentration conformation constants containing corresponding coupling derived described determined DISCUSSION effect electron energy equation esters ethanol ether expected experimental experiments factor Figure followed formation formed further gave give given hydrogen hydrolysis increase indicate initial intermediate involving kinetic less measured mechanism method methyl mixing mixture mole molecular molecule nitration observed obtained occurs organic oxidation oxygen peaks peroxide Phys plot position possible prepared present pressure proton radical rate constants ratio reaction reactivity reduced relative reported requires resonance respectively ring salts shifts showed shown similar sodium solution solvent spectra spectrum structure studied substituent suggested Table temperature values yield