Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 464
... Oxidation products of homologues of cinnamic acid (. Again it is clear that direct attack on the double bond is the preponderating oxidative route . A test showed that the oxidation of pyruvic acid occurred very rapidly indeed . Oxidation ...
... Oxidation products of homologues of cinnamic acid (. Again it is clear that direct attack on the double bond is the preponderating oxidative route . A test showed that the oxidation of pyruvic acid occurred very rapidly indeed . Oxidation ...
Page 465
... Oxidation of 6 - Phenylhex - 2 - enoic Acid . - Oxidation of 6 - phenylhex - 2 - enoic acid ( see Table 6 ) clearly involves both double - bond attack , since 4 - phenylbutanal , is formed , together with 4 - phenylbut - 3 - enal which ...
... Oxidation of 6 - Phenylhex - 2 - enoic Acid . - Oxidation of 6 - phenylhex - 2 - enoic acid ( see Table 6 ) clearly involves both double - bond attack , since 4 - phenylbutanal , is formed , together with 4 - phenylbut - 3 - enal which ...
Page 466
... oxidation occurs concurrently at the double - bond and , in the main , leads to complete bond - fission . Both with 2 - methyl - 3 - phenylacrylic acid and with 2,3 - di- phenylacrylic acid some evidence was obtained that this oxidation ...
... oxidation occurs concurrently at the double - bond and , in the main , leads to complete bond - fission . Both with 2 - methyl - 3 - phenylacrylic acid and with 2,3 - di- phenylacrylic acid some evidence was obtained that this oxidation ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
Copyright | |
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absorption acetic acid Acta alcohol alkyl Amer amine angles anion aqueous aromatic ation benzene bond bromide calculated carbon tetrachloride CH₂ Chem chemical shifts Chemistry Chim chloride CO₂H coefficients compounds concentration conformation corresponding coupling constants decomposition derived di-imine dioxan dipole effect electron equation esters ethanol ether experimental Figure first-order fluorine formation formed hydrogen hydrolysis hydroxide hypochlorous acid interaction intermediate iodide irradiation isomer isomerisation isopropyl k₁ ketone kinetic measured mechanism mercuric mesitylene method methyl mixture mole mole-¹ molecular molecule n.m.r. spectra nitration nitrogen observed obtained olefin oxidation oxygen peaks peroxide phenyl Phys plot polymer proton radical rate constants ratio reactants reaction reactivity reduced relative resonance ring salts showed shown similar singlet sodium solution solvent solvolysis spectrum steric steric effect structure substituent sulphoxide t-butyl Table temperature titanium(III triethyl phosphite values