Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 464
... Oxidation products of homologues of cinnamic acid (. Again it is clear that direct attack on the double bond is the preponderating oxidative route . A test showed that the oxidation of pyruvic acid occurred very rapidly indeed . Oxidation ...
... Oxidation products of homologues of cinnamic acid (. Again it is clear that direct attack on the double bond is the preponderating oxidative route . A test showed that the oxidation of pyruvic acid occurred very rapidly indeed . Oxidation ...
Page 465
... Oxidation of 6 - Phenylhex - 2 - enoic Acid . - Oxidation of 6 - phenylhex - 2 - enoic acid ( see Table 6 ) clearly involves both double - bond attack , since 4 - phenylbutanal , is formed , together with 4 - phenylbut - 3 - enal which ...
... Oxidation of 6 - Phenylhex - 2 - enoic Acid . - Oxidation of 6 - phenylhex - 2 - enoic acid ( see Table 6 ) clearly involves both double - bond attack , since 4 - phenylbutanal , is formed , together with 4 - phenylbut - 3 - enal which ...
Page 466
... oxidation occurs concurrently at the double - bond and , in the main , leads to complete bond - fission . Both with 2 - methyl - 3 - phenylacrylic acid and with 2,3 - di- phenylacrylic acid some evidence was obtained that this oxidation ...
... oxidation occurs concurrently at the double - bond and , in the main , leads to complete bond - fission . Both with 2 - methyl - 3 - phenylacrylic acid and with 2,3 - di- phenylacrylic acid some evidence was obtained that this oxidation ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
Copyright | |
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absorption acetic acid activation added addition alcohol Amer analysis angles appears aqueous atom base benzene bond bromide calculated carbon carbon tetrachloride Chem chemical chloride compared complex compounds concentration conformation constants containing corresponding coupling derived described determined DISCUSSION effect electron energy equation esters ethanol ether expected experimental experiments factor Figure followed formation formed further gave give given hydrogen hydrolysis increase indicate initial intermediate involving kinetic less measured mechanism method methyl mixing mixture mole molecular molecule nitration observed obtained occurs organic oxidation oxygen peaks peroxide Phys plot position possible prepared present pressure proton radical rate constants ratio reaction reactivity reduced relative reported requires resonance respectively ring salts shifts showed shown similar sodium solution solvent spectra spectrum structure studied substituent suggested Table temperature values yield