Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 411
... oxygen towards this radical . We should expect the initial reaction of the phenyl radical with oxygen to yield the phenyl peroxy - radical and thence , by reduction ( the unknown ) phenyl hydro- peroxide . Possibly this species ...
... oxygen towards this radical . We should expect the initial reaction of the phenyl radical with oxygen to yield the phenyl peroxy - radical and thence , by reduction ( the unknown ) phenyl hydro- peroxide . Possibly this species ...
Page 477
... oxygen - TEB ratio in vessel A ( TEB pressure range 2-7 torr ; runs with pure oxygen ) ; I , total condensable hydrocarbons ; II , liquid nitrogen trap products ; III , no . of B - C bonds broken ( see text ) ; IV , acetaldehyde Figure ...
... oxygen - TEB ratio in vessel A ( TEB pressure range 2-7 torr ; runs with pure oxygen ) ; I , total condensable hydrocarbons ; II , liquid nitrogen trap products ; III , no . of B - C bonds broken ( see text ) ; IV , acetaldehyde Figure ...
Page 478
... oxygen- TEB ratios . ( ii ) Distribution of products . This has been shown to be nearly independent of surface and added inert gases for ethane . With the oxidant a nitrogen - oxygen mixture ( ca. 15 : 1 ) in vessel A , butane increased ...
... oxygen- TEB ratios . ( ii ) Distribution of products . This has been shown to be nearly independent of surface and added inert gases for ethane . With the oxidant a nitrogen - oxygen mixture ( ca. 15 : 1 ) in vessel A , butane increased ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
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absorption acetic acid activation added addition alcohol Amer analysis angles appears aqueous atom base benzene bond bromide calculated carbon carbon tetrachloride Chem chemical chloride compared complex compounds concentration conformation constants containing corresponding coupling derived described determined DISCUSSION effect electron energy equation esters ethanol ether expected experimental experiments factor Figure followed formation formed further gave give given hydrogen hydrolysis increase indicate initial intermediate involving kinetic less measured mechanism method methyl mixing mixture mole molecular molecule nitration observed obtained occurs organic oxidation oxygen peaks peroxide Phys plot position possible prepared present pressure proton radical rate constants ratio reaction reactivity reduced relative reported requires resonance respectively ring salts shifts showed shown similar sodium solution solvent spectra spectrum structure studied substituent suggested Table temperature values yield