Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 120
Chemical Society (Great Britain). Aroyl Peroxides . Part V.t Decomposition of Benzoyl Peroxide in By P. Lewis and Gareth H. Williams , * ‡ Birkbeck College , Malet Street , W.C.1 . The kinetics and products of the reaction of benzoyl ...
Chemical Society (Great Britain). Aroyl Peroxides . Part V.t Decomposition of Benzoyl Peroxide in By P. Lewis and Gareth H. Williams , * ‡ Birkbeck College , Malet Street , W.C.1 . The kinetics and products of the reaction of benzoyl ...
Page 395
... peroxide . Thus , when 0-6м - formic acid was oxidised with the titanium ( III ) -peroxide system ( with 0-05м - hydrogen peroxide ) and 1-2M - methanol was introduced at the second mixing point , only the spectrum of CH , OH was CH2OH ...
... peroxide . Thus , when 0-6м - formic acid was oxidised with the titanium ( III ) -peroxide system ( with 0-05м - hydrogen peroxide ) and 1-2M - methanol was introduced at the second mixing point , only the spectrum of CH , OH was CH2OH ...
Page 397
... peroxide system in acidic conditions.27 Finally , maleic acid gave a spectrum identi- cal with that from the titanium ( III ) -peroxide system which has been attributed 21 to the adduct ( VIII ) . The last result demonstrates clearly ...
... peroxide system in acidic conditions.27 Finally , maleic acid gave a spectrum identi- cal with that from the titanium ( III ) -peroxide system which has been attributed 21 to the adduct ( VIII ) . The last result demonstrates clearly ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
Copyright | |
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absorption acetic acid activation added addition alcohol Amer analysis angles appears aqueous atom base benzene bond bromide calculated carbon carbon tetrachloride Chem chemical chloride compared complex compounds concentration conformation constants containing corresponding coupling derived described determined DISCUSSION effect electron energy equation esters ethanol ether expected experimental experiments factor Figure followed formation formed further gave give given hydrogen hydrolysis increase indicate initial intermediate involving kinetic less measured mechanism method methyl mixing mixture mole molecular molecule nitration observed obtained occurs organic oxidation oxygen peaks peroxide Phys plot position possible prepared present pressure proton radical rate constants ratio reaction reactivity reduced relative reported requires resonance respectively ring salts shifts showed shown similar sodium solution solvent spectra spectrum structure studied substituent suggested Table temperature values yield