Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 70
... plot of log A against t should give a straight line of gradient ( k1 + kg ) / 2 · 303 and a plot of B against [ e ( k1 + kg ) t — e ̄k2t ] should give a straight line of gradient k1 and k ̧ can then R2 ( k1 + kg ) be determined if k is ...
... plot of log A against t should give a straight line of gradient ( k1 + kg ) / 2 · 303 and a plot of B against [ e ( k1 + kg ) t — e ̄k2t ] should give a straight line of gradient k1 and k ̧ can then R2 ( k1 + kg ) be determined if k is ...
Page 155
... plot A of Figure 1 , and the corresponding plot for 2 - tritionaphthalenes in plot A of Figure 2. ( The only reason for not combining these plots , which should have the same slope , is that there would be too many points for clarity ) ...
... plot A of Figure 1 , and the corresponding plot for 2 - tritionaphthalenes in plot A of Figure 2. ( The only reason for not combining these plots , which should have the same slope , is that there would be too many points for clarity ) ...
Page 158
... Plot of b1 against ( A ) —qij and ( B ) q1w ( the numbers on the points are the ij values ) is plotted against qw , the charge on atom i in the Wheland intermediate . The latter plot is the more satisfactory , and the points lie ...
... Plot of b1 against ( A ) —qij and ( B ) q1w ( the numbers on the points are the ij values ) is plotted against qw , the charge on atom i in the Wheland intermediate . The latter plot is the more satisfactory , and the points lie ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
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absorption acetic acid Acta alcohol alkyl Amer amine angles anion aqueous aromatic ation benzene bond bromide calculated carbon tetrachloride CH₂ Chem chemical shifts Chemistry Chim chloride CO₂H coefficients compounds concentration conformation corresponding coupling constants decomposition derived di-imine dioxan dipole effect electron equation esters ethanol ether experimental Figure first-order fluorine formation formed hydrogen hydrolysis hydroxide hypochlorous acid interaction intermediate iodide irradiation isomer isomerisation isopropyl k₁ ketone kinetic measured mechanism mercuric mesitylene method methyl mixture mole mole-¹ molecular molecule n.m.r. spectra nitration nitrogen observed obtained olefin oxidation oxygen peaks peroxide phenyl Phys plot polymer proton radical rate constants ratio reactants reaction reactivity reduced relative resonance ring salts showed shown similar singlet sodium solution solvent solvolysis spectrum steric steric effect structure substituent sulphoxide t-butyl Table temperature titanium(III triethyl phosphite values