Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 51
... rate constants obtained from the logarith- mic plots were independent of initial pressure from 20— 120 torr . Experiments in the temperature range 342-441 ° gave the rate constants summarised in Table 1. The plot of log ( rate constant ) ...
... rate constants obtained from the logarith- mic plots were independent of initial pressure from 20— 120 torr . Experiments in the temperature range 342-441 ° gave the rate constants summarised in Table 1. The plot of log ( rate constant ) ...
Page 146
... rate constant for benzylidene formation , and the relationship between the appropriate Hammett's a - constants , rate constants , and n.m.r. chemical - shift values investigated . The Ratio of ' Metastable Peak ' Abundances in Relation.
... rate constant for benzylidene formation , and the relationship between the appropriate Hammett's a - constants , rate constants , and n.m.r. chemical - shift values investigated . The Ratio of ' Metastable Peak ' Abundances in Relation.
Page 283
... rate , pursu- ing the usual second - order kinetic course . The measured rate constants are given in Table 12 . TABLE 12 Second - order rate constants of the reaction of methyl- mercuric chloride with 1 - cyano - 1 - ethoxycarbonyl ...
... rate , pursu- ing the usual second - order kinetic course . The measured rate constants are given in Table 12 . TABLE 12 Second - order rate constants of the reaction of methyl- mercuric chloride with 1 - cyano - 1 - ethoxycarbonyl ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
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absorption acetic acid activation added addition alcohol Amer analysis angles appears aqueous atom base benzene bond bromide calculated carbon carbon tetrachloride Chem chemical chloride compared complex compounds concentration conformation constants containing corresponding coupling derived described determined DISCUSSION effect electron energy equation esters ethanol ether expected experimental experiments factor Figure followed formation formed further gave give given hydrogen hydrolysis increase indicate initial intermediate involving kinetic less measured mechanism method methyl mixing mixture mole molecular molecule nitration observed obtained occurs organic oxidation oxygen peaks peroxide Phys plot position possible prepared present pressure proton radical rate constants ratio reaction reactivity reduced relative reported requires resonance respectively ring salts shifts showed shown similar sodium solution solvent spectra spectrum structure studied substituent suggested Table temperature values yield