Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 265
... salts with the comparable data for the saturated cyclic phosphonium salts ( XI ; R1 = H , R2 = Ph ) and ( XII ) is of great interest . Hydrolysis of these salts occurs with fission of the exocyclic phenyl group to form the corresponding ...
... salts with the comparable data for the saturated cyclic phosphonium salts ( XI ; R1 = H , R2 = Ph ) and ( XII ) is of great interest . Hydrolysis of these salts occurs with fission of the exocyclic phenyl group to form the corresponding ...
Page 281
... salts with methyl- ( triphenylphosphine ) gold ( 1 ) ( by the ' direct ' method ) Substi- tuting agent ( 10-4 mole / 1 . ) rates of substitution by corresponding mercuric salts . Except for an anomaly mentioned below , the rates of ...
... salts with methyl- ( triphenylphosphine ) gold ( 1 ) ( by the ' direct ' method ) Substi- tuting agent ( 10-4 mole / 1 . ) rates of substitution by corresponding mercuric salts . Except for an anomaly mentioned below , the rates of ...
Page 284
... salts are irrelevant to its rate . 7. S2 Substitution by Mercuric Salts in Trimethyl- ( triphenylphosphine ) gold ( 111 ) .— Mercuric salts react with this gold ( III ) complex to form a methylmercuric salt and a dimethyl ...
... salts are irrelevant to its rate . 7. S2 Substitution by Mercuric Salts in Trimethyl- ( triphenylphosphine ) gold ( 111 ) .— Mercuric salts react with this gold ( III ) complex to form a methylmercuric salt and a dimethyl ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
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absorption acetic acid Acta alcohol alkyl Amer amine angles anion aqueous aromatic ation benzene bond bromide calculated carbon tetrachloride CH₂ Chem chemical shifts Chemistry Chim chloride CO₂H coefficients compounds concentration conformation corresponding coupling constants decomposition derived di-imine dioxan dipole effect electron equation esters ethanol ether experimental Figure first-order fluorine formation formed hydrogen hydrolysis hydroxide hypochlorous acid interaction intermediate iodide irradiation isomer isomerisation isopropyl k₁ ketone kinetic measured mechanism mercuric mesitylene method methyl mixture mole mole-¹ molecular molecule n.m.r. spectra nitration nitrogen observed obtained olefin oxidation oxygen peaks peroxide phenyl Phys plot polymer proton radical rate constants ratio reactants reaction reactivity reduced relative resonance ring salts showed shown similar singlet sodium solution solvent solvolysis spectrum steric steric effect structure substituent sulphoxide t-butyl Table temperature titanium(III triethyl phosphite values