Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 71
... Sodium deuteri- oxide in D2O . Kinetics in Deuterium Oxide . - Sodium deuteroxide in deuterium oxide was made by dissolution of sodium in deuterium oxide under dry nitrogen . Kinetic procedures for following the isomerisation of pent ...
... Sodium deuteri- oxide in D2O . Kinetics in Deuterium Oxide . - Sodium deuteroxide in deuterium oxide was made by dissolution of sodium in deuterium oxide under dry nitrogen . Kinetic procedures for following the isomerisation of pent ...
Page 246
... Sodium Benzenethiolate in Methanol .— ( a ) From cis - p- anisyl 2 - chlorovinyl ketone ( Ia ) . To a solution of chloro- vinyl ketone ( Ia ) ( 0.20 g . , 1 x 10-3 mole ) in absolute methanol ( 30 ml . ) a solution of sodium ...
... Sodium Benzenethiolate in Methanol .— ( a ) From cis - p- anisyl 2 - chlorovinyl ketone ( Ia ) . To a solution of chloro- vinyl ketone ( Ia ) ( 0.20 g . , 1 x 10-3 mole ) in absolute methanol ( 30 ml . ) a solution of sodium ...
Page 330
... Sodium Hydroxide and M. El - Ghariani , Chemistry Department , The University , Durham The interactions of picric acid with aqueous sodium sulphite and with sodium hydroxide have been examined by visible and 1H n.m.r. spectroscopy ...
... Sodium Hydroxide and M. El - Ghariani , Chemistry Department , The University , Durham The interactions of picric acid with aqueous sodium sulphite and with sodium hydroxide have been examined by visible and 1H n.m.r. spectroscopy ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
Copyright | |
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absorption acetic acid Acta alcohol alkyl Amer amine angles anion aqueous aromatic ation benzene bond bromide calculated carbanion carbon tetrachloride CH₂ Chem chemical shifts Chemistry Chim chloride CO₂H compounds concentration conformation corresponding coupling constants decomposition derived di-imine dioxan dipole effect electron equation esters ethanol ether experimental Figure first-order fluorine formation formed hydrogen hydrolysis hydroxide hypochlorous acid interaction intermediate iodide irradiation isomer isomerisation isopropyl k₁ ketone kinetic measured mechanism mercuric mesitylene method methyl mixture mole mole-¹ molecular molecule n.m.r. spectra nitration nitrogen observed obtained olefin oxidation oxygen peaks peroxide phenyl Phys plot polymer proton radical rate constants ratio reactants reaction reactivity reduced relative resonance ring salts showed shown similar singlet sodium solution solvent solvolysis spectrum steric steric effect structure substituent sulphoxide t-butyl Table temperature titanium(III triethyl phosphite values