Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 94
... studied between 530 and 762 ° in a flow system . Below 600 ° dehydration is second - order : k = 109.52 exp ... studied in a flow system over a range of 230 ° which overlaps with ranges studied in previous static and flow work ...
... studied between 530 and 762 ° in a flow system . Below 600 ° dehydration is second - order : k = 109.52 exp ... studied in a flow system over a range of 230 ° which overlaps with ranges studied in previous static and flow work ...
Page 290
... studied and their rates measured . With both reagents and both substrates direct substitution was observed . In contrast with the behaviour of cis - chloro- and bromo - styrenes , the elimination mechanism is not operative . The ...
... studied and their rates measured . With both reagents and both substrates direct substitution was observed . In contrast with the behaviour of cis - chloro- and bromo - styrenes , the elimination mechanism is not operative . The ...
Page 366
... studied and the activation parameters have been determined . At 45.0 ° , the rate of decomposition is 2890 - fold greater than that fort - butyl chloride , a factor which is considerably higher than the corresponding values of 28-51 in ...
... studied and the activation parameters have been determined . At 45.0 ° , the rate of decomposition is 2890 - fold greater than that fort - butyl chloride , a factor which is considerably higher than the corresponding values of 28-51 in ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
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absorption acetic acid Acta alcohol alkyl Amer amine angles anion aqueous aromatic ation benzene bond bromide calculated carbon tetrachloride CH₂ Chem chemical shifts Chemistry Chim chloride CO₂H coefficients compounds concentration conformation corresponding coupling constants decomposition derived di-imine dioxan dipole effect electron equation esters ethanol ether experimental Figure first-order fluorine formation formed hydrogen hydrolysis hydroxide hypochlorous acid interaction intermediate iodide irradiation isomer isomerisation isopropyl k₁ ketone kinetic measured mechanism mercuric mesitylene method methyl mixture mole mole-¹ molecular molecule n.m.r. spectra nitration nitrogen observed obtained olefin oxidation oxygen peaks peroxide phenyl Phys plot polymer proton radical rate constants ratio reactants reaction reactivity reduced relative resonance ring salts showed shown similar singlet sodium solution solvent solvolysis spectrum steric steric effect structure substituent sulphoxide t-butyl Table temperature titanium(III triethyl phosphite values