Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 54
... suggested for the hydrolysis of benzyl fluoride would lead to the initial formation of PhCF , OH , which would be expected to be rapidly converted into PhCO2H . The observed sub- stituent effects and acidity dependence suggest that the ...
... suggested for the hydrolysis of benzyl fluoride would lead to the initial formation of PhCF , OH , which would be expected to be rapidly converted into PhCO2H . The observed sub- stituent effects and acidity dependence suggest that the ...
Page 77
... suggested several years ago.1 While the blue -complexes of the amines are visually re- cognisable , the occurrence of the o - complexes ( I ) was inferred by indirect evidence . The kinetics had shown NR2 + ( NC ) , C = C ( CN , 2 ...
... suggested several years ago.1 While the blue -complexes of the amines are visually re- cognisable , the occurrence of the o - complexes ( I ) was inferred by indirect evidence . The kinetics had shown NR2 + ( NC ) , C = C ( CN , 2 ...
Page 306
... suggested that 12 % of the SH radicals disappear by reaction ( 5 ) and 87 % by reaction ( 3 ) . In the presence of acetylene further reactions of both hydrogen atoms and SH radicals are possible and the SH radicals can take part in ...
... suggested that 12 % of the SH radicals disappear by reaction ( 5 ) and 87 % by reaction ( 3 ) . In the presence of acetylene further reactions of both hydrogen atoms and SH radicals are possible and the SH radicals can take part in ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
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absorption acetic acid activation added addition alcohol Amer analysis angles appears aqueous atom base benzene bond bromide calculated carbon carbon tetrachloride Chem chemical chloride compared complex compounds concentration conformation constants containing corresponding coupling derived described determined DISCUSSION effect electron energy equation esters ethanol ether expected experimental experiments factor Figure followed formation formed further gave give given hydrogen hydrolysis increase indicate initial intermediate involving kinetic less measured mechanism method methyl mixing mixture mole molecular molecule nitration observed obtained occurs organic oxidation oxygen peaks peroxide Phys plot position possible prepared present pressure proton radical rate constants ratio reaction reactivity reduced relative reported requires resonance respectively ring salts shifts showed shown similar sodium solution solvent spectra spectrum structure studied substituent suggested Table temperature values yield