Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 54
... suggested for the hydrolysis of benzyl fluoride would lead to the initial formation of PhCF , OH , which would be expected to be rapidly converted into PhCO2H . The observed sub- stituent effects and acidity dependence suggest that the ...
... suggested for the hydrolysis of benzyl fluoride would lead to the initial formation of PhCF , OH , which would be expected to be rapidly converted into PhCO2H . The observed sub- stituent effects and acidity dependence suggest that the ...
Page 77
... suggested several years ago.1 While the blue -complexes of the amines are visually re- cognisable , the occurrence of the o - complexes ( I ) was inferred by indirect evidence . The kinetics had shown NR2 + ( NC ) , C = C ( CN , 2 ...
... suggested several years ago.1 While the blue -complexes of the amines are visually re- cognisable , the occurrence of the o - complexes ( I ) was inferred by indirect evidence . The kinetics had shown NR2 + ( NC ) , C = C ( CN , 2 ...
Page 306
... suggested that 12 % of the SH radicals disappear by reaction ( 5 ) and 87 % by reaction ( 3 ) . In the presence of acetylene further reactions of both hydrogen atoms and SH radicals are possible and the SH radicals can take part in ...
... suggested that 12 % of the SH radicals disappear by reaction ( 5 ) and 87 % by reaction ( 3 ) . In the presence of acetylene further reactions of both hydrogen atoms and SH radicals are possible and the SH radicals can take part in ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
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absorption acetic acid Acta alcohol alkyl Amer amine angles anion aqueous aromatic ation benzene bond bromide calculated carbon tetrachloride CH₂ Chem chemical shifts Chemistry Chim chloride CO₂H coefficients compounds concentration conformation corresponding coupling constants decomposition derived di-imine dioxan dipole effect electron equation esters ethanol ether experimental Figure first-order fluorine formation formed hydrogen hydrolysis hydroxide hypochlorous acid interaction intermediate iodide irradiation isomer isomerisation isopropyl k₁ ketone kinetic measured mechanism mercuric mesitylene method methyl mixture mole mole-¹ molecular molecule n.m.r. spectra nitration nitrogen observed obtained olefin oxidation oxygen peaks peroxide phenyl Phys plot polymer proton radical rate constants ratio reactants reaction reactivity reduced relative resonance ring salts showed shown similar singlet sodium solution solvent solvolysis spectrum steric steric effect structure substituent sulphoxide t-butyl Table temperature titanium(III triethyl phosphite values