Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 123
... yield of benzoic acid was low and increased steadily at higher [ Plo . The combined yields of acid and biaryl accounted for less than 50 % of the peroxide decomposed . The total yield of fluorophenyl benzoates was low but in- creased ...
... yield of benzoic acid was low and increased steadily at higher [ Plo . The combined yields of acid and biaryl accounted for less than 50 % of the peroxide decomposed . The total yield of fluorophenyl benzoates was low but in- creased ...
Page 285
... ( yield 80 % ) , m.p. 248-249 ° ( from benzene - ligroin ) ( Found : C , 43-7 ; H , 3.1 ; Au , 39.6 . Calc . for C18H15AuCIP : C , 43-7 ; H , 3.0 ; Au , 39.8 % ) , v , 331s and 323ms cm . - 1 , max . 269 and 275 mu ...
... ( yield 80 % ) , m.p. 248-249 ° ( from benzene - ligroin ) ( Found : C , 43-7 ; H , 3.1 ; Au , 39.6 . Calc . for C18H15AuCIP : C , 43-7 ; H , 3.0 ; Au , 39.8 % ) , v , 331s and 323ms cm . - 1 , max . 269 and 275 mu ...
Page 422
... yield of recovered Yield of 1,3- dichloroacetone Active 1,3- Specific activity dichloroacetone [ Ag + ] ( m ) added ( g . ) material ( % ) 0.427 12,000 76 0.005 0.576 14,640 71 0.02 0.684 20,130 38 0.09 0.712 27,150 0.12 0.780 29,070 7 ...
... yield of recovered Yield of 1,3- dichloroacetone Active 1,3- Specific activity dichloroacetone [ Ag + ] ( m ) added ( g . ) material ( % ) 0.427 12,000 76 0.005 0.576 14,640 71 0.02 0.684 20,130 38 0.09 0.712 27,150 0.12 0.780 29,070 7 ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
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absorption acetic acid Acta alcohol alkyl Amer amine angles anion aqueous aromatic ation benzene bond bromide calculated carbon tetrachloride CH₂ Chem chemical shifts Chemistry Chim chloride CO₂H coefficients compounds concentration conformation corresponding coupling constants decomposition derived di-imine dioxan dipole effect electron equation esters ethanol ether experimental Figure first-order fluorine formation formed hydrogen hydrolysis hydroxide hypochlorous acid interaction intermediate iodide irradiation isomer isomerisation isopropyl k₁ ketone kinetic measured mechanism mercuric mesitylene method methyl mixture mole mole-¹ molecular molecule n.m.r. spectra nitration nitrogen observed obtained olefin oxidation oxygen peaks peroxide phenyl Phys plot polymer proton radical rate constants ratio reactants reaction reactivity reduced relative resonance ring salts showed shown similar singlet sodium solution solvent solvolysis spectrum steric steric effect structure substituent sulphoxide t-butyl Table temperature titanium(III triethyl phosphite values