Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 123
... yield of benzoic acid was low and increased steadily at higher [ Plo . The combined yields of acid and biaryl accounted for less than 50 % of the peroxide decomposed . The total yield of fluorophenyl benzoates was low but in- creased ...
... yield of benzoic acid was low and increased steadily at higher [ Plo . The combined yields of acid and biaryl accounted for less than 50 % of the peroxide decomposed . The total yield of fluorophenyl benzoates was low but in- creased ...
Page 285
... ( yield 80 % ) , m.p. 248-249 ° ( from benzene - ligroin ) ( Found : C , 43-7 ; H , 3.1 ; Au , 39.6 . Calc . for C18H15AuCIP : C , 43-7 ; H , 3.0 ; Au , 39.8 % ) , v , 331s and 323ms cm . - 1 , max . 269 and 275 mu ...
... ( yield 80 % ) , m.p. 248-249 ° ( from benzene - ligroin ) ( Found : C , 43-7 ; H , 3.1 ; Au , 39.6 . Calc . for C18H15AuCIP : C , 43-7 ; H , 3.0 ; Au , 39.8 % ) , v , 331s and 323ms cm . - 1 , max . 269 and 275 mu ...
Page 422
... yield of recovered Yield of 1,3- dichloroacetone Active 1,3- Specific activity dichloroacetone [ Ag + ] ( m ) added ( g . ) material ( % ) 0.427 12,000 76 0.005 0.576 14,640 71 0.02 0.684 20,130 38 0.09 0.712 27,150 0.12 0.780 29,070 7 ...
... yield of recovered Yield of 1,3- dichloroacetone Active 1,3- Specific activity dichloroacetone [ Ag + ] ( m ) added ( g . ) material ( % ) 0.427 12,000 76 0.005 0.576 14,640 71 0.02 0.684 20,130 38 0.09 0.712 27,150 0.12 0.780 29,070 7 ...
Contents
Physical organic chemistry | 1 |
Aromatic reactivity Part XXXVIII Protodesilylation of 12dihydrobenzocyclobutene indan and tetralin | 12 |
Aromatic reactivity Part XL Additional substituent effects in protodetrimethylsilylation | 21 |
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absorption acetic acid activation added addition alcohol Amer analysis angles appears aqueous atom base benzene bond bromide calculated carbon carbon tetrachloride Chem chemical chloride compared complex compounds concentration conformation constants containing corresponding coupling derived described determined DISCUSSION effect electron energy equation esters ethanol ether expected experimental experiments factor Figure followed formation formed further gave give given hydrogen hydrolysis increase indicate initial intermediate involving kinetic less measured mechanism method methyl mixing mixture mole molecular molecule nitration observed obtained occurs organic oxidation oxygen peaks peroxide Phys plot position possible prepared present pressure proton radical rate constants ratio reaction reactivity reduced relative reported requires resonance respectively ring salts shifts showed shown similar sodium solution solvent spectra spectrum structure studied substituent suggested Table temperature values yield