Quarterly Journal of the Chemical Society of London, Issue 1, Pages 1-776 |
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Page 106
... sulphur . The copper atom is co - planar with the three sulphur atoms , while the phosphorus atoms P ( 1 ) , P ( 2 ) , and P ( 3 ) lie only -0.46 , +0.28 and +0.76 Å , respectively , from this plane . Bond angles about copper are close ...
... sulphur . The copper atom is co - planar with the three sulphur atoms , while the phosphorus atoms P ( 1 ) , P ( 2 ) , and P ( 3 ) lie only -0.46 , +0.28 and +0.76 Å , respectively , from this plane . Bond angles about copper are close ...
Page 372
... Sulphur in Oleum . The Ion S , + By M. STILLINGS , M. C. R. SYMONS , * and J. G. WILKINSON ( Department of Chemistry , The University , Leicester LE1 7RH ) TABLE 1 Optical parameters and assignments for various cations of sulphur S1 + ...
... Sulphur in Oleum . The Ion S , + By M. STILLINGS , M. C. R. SYMONS , * and J. G. WILKINSON ( Department of Chemistry , The University , Leicester LE1 7RH ) TABLE 1 Optical parameters and assignments for various cations of sulphur S1 + ...
Page 373
... sulphur atoms per radical is excluded . The results suggest either one or possibly two equivalent atoms and the large number of poorly resolved features suggests at least two types of Sulphur atoms . We tentatively offer the following ...
... sulphur atoms per radical is excluded . The results suggest either one or possibly two equivalent atoms and the large number of poorly resolved features suggests at least two types of Sulphur atoms . We tentatively offer the following ...
Contents
Page | 1 |
Electrochemical Indications of New Oxidation States in Transitionmetal Dicarbollide Complexes | 8 |
Crystal Structure and Bonding in the Dinuclear Complexes CHW SPhMCO M Cr | 14 |
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acetate acid Acta adduct alcohol alkaloids alkyl Amer analysis anion aqueous aromatic assigned atoms band benzene carbon carbonyl cation chelate Chem chemical shifts Chemical Society Chim chloride cm-¹ co-ordination Comm complexes compounds configuration confirmed coupling Crystal Structure cyclopropane Department of Chemistry derivatives double bond doublet electron ester ether Figure formation formed gave H₂O hydride hydrogen hydrolysis i.r. spectrum ibid indicate Inorg intermediate irradiation isolated isomer ketone ligand metal methanol methyl methylene mixture molecular molecule n.m.r. spectrum nitrogen observed obtained olefinic oxidation oxygen phenyl phosphine photolysis Phys presence protons pyridine radical ratio reaction rearrangement Received reported resonance ring room temperature shown shows similar singlet sodium solution solvent space group spectra spectroscopy stereochemistry studies substituted suggested sulphur Summary synthesis Table Tetrahedron Letters tetrahydrofuran tion triphenylphosphine tritium University values X-ray yield