Journal of the Chemical SocietyThe Society., 1964 |
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Page 4570
... Complexes of Unsaturated Tertiary Phosphines and Arsines . Part I. Complexes of Ligands containing the Pent - 4 - enyl Group . M. A. BENNETT , H. W. KOUWENHOVEN , J. LEWIS , and R. S. NYHOLM . Chelate complexes of general formula LPtX ...
... Complexes of Unsaturated Tertiary Phosphines and Arsines . Part I. Complexes of Ligands containing the Pent - 4 - enyl Group . M. A. BENNETT , H. W. KOUWENHOVEN , J. LEWIS , and R. S. NYHOLM . Chelate complexes of general formula LPtX ...
Page 4571
... complexes are diamagnetic , non - conducting in nitrobenzene , and essentially monomeric in acetone and chloroform , although there appears to be some association in chloroform . The infrared spectra of the complexes LPtX2 ( L = CH ...
... complexes are diamagnetic , non - conducting in nitrobenzene , and essentially monomeric in acetone and chloroform , although there appears to be some association in chloroform . The infrared spectra of the complexes LPtX2 ( L = CH ...
Page 4572
... complexes of platinum ( 11 ) .3 There is no evidence for a bisthiocyanate chelate complex with the olefinic phosphine . The configuration of the platinum complexes has been determined by measuring the infrared spectra in the range 450 ...
... complexes of platinum ( 11 ) .3 There is no evidence for a bisthiocyanate chelate complex with the olefinic phosphine . The configuration of the platinum complexes has been determined by measuring the infrared spectra in the range 450 ...
Contents
4028 | 3507 |
Nucleophilic reactivity Part V The reaction between amines and ethyl meth | 3513 |
Molecular polarisability Dipole moments molar Kerr constants and apparent | 3523 |
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absorption acetic acid acetic anhydride acetone acetoxylation acetyl added alcohol alkaline alumina aluminium Amer amine atoms band benzene benzyl bond bromide Calc carbon carbonyl CH₂ chabazite Chem chloride chloroform chromatography cm.¹ compounds concentration crystals decomp derivatives diethyl diluted dimethylformamide diol dissolved distilled dried ester ethanol ethyl acetate evaporated EXPERIMENTAL extracted with ether filtrate formation Found fraction gave give heated hydrochloric acid hydrochloride hydrogen hydrolysis hydroxyl infrared iodide isomers K₁ ketone kinetic light petroleum lithium lithium aluminium hydride m. p. and mixed mixed m. p. mixture mole molecules needles nitrate nitric acid nitrogen o-xylene obtained optical oxide oxygen petroleum b. p. phenol picrate potassium precipitated prepared proton pyridine rate constants reaction recrystallised refluxed requires residue room temperature salt sodium hydroxide solvent spectra spectrum stirred structure substitution sulphuric acid Table values washed yield